| 1448460-96-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1448460-96-5
• 化学式: C₅₄H₅₈LuN₇P₂Si₂
• 分子量: 1098.19
• InChiKey: AXQOJYILBGNLCP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 以 甲苯 为溶剂， 反应 5.0h， 生成
  参考文献：
  名称：

  Organolutetium-Mediated Dearomatization and Functionalization of Pyrimidine Rings

  摘要：

  The synthesis of a pentadentate NNNNN bis(phosphinimine)carbazole pincer ligand bearing two pyrimidine N-aryl rings is reported. A dialkyl lutetium complex of the ligand, prepared by alkane elimination with Lu-(CH2SiMe3)(3)(THF)(2), was found to undergo an unusual transformation involving a double alkyl shift whereby the -CH2SiMe3 groups on the metal migrated to both pyrimidine rings. This migration afforded a final product that featured alkyl-functionalized, dearomatized ligand pyrimidine rings.

  DOI：

  10.1021/om400413e
• 作为产物：
  描述：

  Lu(trimethylsilylmethyl)3(tetrahydrofuran)2 、 [8-[diphenyl(pyrimidin-2-ylimino)-lambda5-phosphanyl]-3,6-dimethyl-9H-carbazol-1-yl]-diphenyl-pyrimidin-2-ylimino-lambda5-phosphane 以 氘代甲苯 为溶剂， 生成
  参考文献：
  名称：

  Organolutetium-Mediated Dearomatization and Functionalization of Pyrimidine Rings

  摘要：

  The synthesis of a pentadentate NNNNN bis(phosphinimine)carbazole pincer ligand bearing two pyrimidine N-aryl rings is reported. A dialkyl lutetium complex of the ligand, prepared by alkane elimination with Lu-(CH2SiMe3)(3)(THF)(2), was found to undergo an unusual transformation involving a double alkyl shift whereby the -CH2SiMe3 groups on the metal migrated to both pyrimidine rings. This migration afforded a final product that featured alkyl-functionalized, dearomatized ligand pyrimidine rings.

  DOI：

  10.1021/om400413e