(E)-N,3-ditosylbenzo[d]thiazol-2(3H)-imine | 1350554-14-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-N,3-ditosylbenzo[d]thiazol-2(3H)-imine
• CAS: 1350554-14-1
• 化学式: C₂₁H₁₈N₂O₄S₃
• 分子量: 458.583
• InChiKey: QIYSDPVJGXZOEB-QURGRASLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.85
• 重原子数：
  30.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  85.57
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  N-(benzo[d]thiazol-2-yl)-4-methylbenzenesulfonamide 、 苯磺酰氯 生成 (E)-N,3-ditosylbenzo[d]thiazol-2(3H)-imine
  参考文献：
  名称：

  ZnO and ZnO-nanoparticles: Efficient and reusable heterogeneous catalysts for one-pot synthesis of N-acylsulfonamides and sulfonate esters

  摘要：

  Commercially available and preparative ZnO nanoparticles are reported as efficient and reusable catalysts for the chemoselective synthesis of N-acylsulfonamides and sulfonate esters. A one-pot sequential sulfonylation and acylation of amines took place to afford the N-acylsulfonamides in excellent yields under solvent-free conditions. The ZnO catalyst can be reused for without significant loss of catalytic activity. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2011.09.010