1-(4-pyridinylformyl)aza-15-crown-5 | 169620-11-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1-(4-pyridinylformyl)aza-15-crown-5
• 英文别名: Pyridin-4-yl(1,4,7,10-tetraoxa-13-azacyclopentadec-13-yl)methanone；pyridin-4-yl(1,4,7,10-tetraoxa-13-azacyclopentadec-13-yl)methanone
• CAS: 169620-11-5
• 化学式: C₁₆H₂₄N₂O₅
• 分子量: 324.377
• InChiKey: AMDFFGIQKVLDBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  70.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  [Re(1,10-phenanthroline)(CO)₃(CH₃CN)](CF₃SO₃) 、 1-(4-pyridinylformyl)aza-15-crown-5 以 四氢呋喃 为溶剂， 生成 [Re(1-(4-pyridinylformyl)aza-15-crown-5)(CO)3(phen)](PF6)
  参考文献：
  名称：

  有机金属rh（I）冠状配合物的合成，光物理，离子结合研究和结构表征

  摘要：

  A series of Re(I) complexes of [Re(L)(CO)(3)Cl] (1, L = L(1) = N-(2-pyridinylmethylene)-2,3,5,6,8,9,11,-12-octahydro-1,4,7,10,13-benzopentaoxacyclononadecan-16-ylamine; 2, L = L(2) = N-(2-pyridinylmethylene)-phenylamine) and [Re(phen)(CO)(3)(L')](+) (3, L' = L(3) = 1-(4-pyridinylformyl)aza-15-crown-5; 4, L' = L(4) = 4-(N,N-diethylformamido)pyridine) have been synthesized and their photophysical and cation binding properties studied. The X-ray crystal structure of 3 has also been determined.

  DOI：

  10.1021/om00009a002

文献信息

• Synthesis, photophysics, ion-binding studies, and structural characterization of organometallic rhenium(I) crown complexes
  作者：Vivian Wing-Wah Yam、Keith Man-Chung Wong、Vicky Wing-Man Lee、Kenneth Kam-Wing Lo、Kung-Kai Cheung

  DOI：10.1021/om00009a002

  日期：1995.9

  A series of Re(I) complexes of [Re(L)(CO)(3)Cl] (1, L = L(1) = N-(2-pyridinylmethylene)-2,3,5,6,8,9,11,-12-octahydro-1,4,7,10,13-benzopentaoxacyclononadecan-16-ylamine; 2, L = L(2) = N-(2-pyridinylmethylene)-phenylamine) and [Re(phen)(CO)(3)(L')](+) (3, L' = L(3) = 1-(4-pyridinylformyl)aza-15-crown-5; 4, L' = L(4) = 4-(N,N-diethylformamido)pyridine) have been synthesized and their photophysical and cation binding properties studied. The X-ray crystal structure of 3 has also been determined.