4-(3-trifluoromethylphenoxy)-phthalonitrile | 905710-36-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(3-trifluoromethylphenoxy)-phthalonitrile
• 英文别名: 4-[3-(Trifluoromethyl)phenoxy]benzene-1,2-dicarbonitrile
• CAS: 905710-36-3
• 化学式: C₁₅H₇F₃N₂O
• 分子量: 288.229
• InChiKey: OCRCFCXFVMHDQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  56.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  正戊醛 、 4-(3-trifluoromethylphenoxy)-phthalonitrile 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 copper dichloride 以 neat (no solvent) 为溶剂， 以57%的产率得到
  参考文献：
  名称：

  Cyclopropanation of alkenes catalyzed by metallophthalocyanines

  摘要：

  Metallophthalocyanines bearing substituents especially electron-withdrawing substituents are found to be efficient catalysts for cyclopropanation of alkenes with EDA. The influences of reaction conditions have been studied, leading to the highest yield of 91% for styrene by using fluorosubstituted ruthenium-phthalocyanine complex. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2005.10.014

文献信息

• RESIN BLENDS CONTAINING A PHTHALONITRILE REACTIVE DILUENT AND A DIPHTHALONITRILE RESIN, PREPREGS, AND ARTICLES
  申请人：3M Innovative Properties Company

  公开号：EP3601215A1

  公开（公告）日：2020-02-05
• [EN] RESIN BLENDS CONTAINING A PHTHALONITRILE REACTIVE DILUENT AND A DIPHTHALONITRILE RESIN, PREPREGS, AND ARTICLES<br/>[FR] MÉLANGES DE RÉSINES CONTENANT UN DILUANT RÉACTIF DE PHTALONITRILE ET UNE RÉSINE DE DIPHTALONITRILE, PRÉIMPRÉGNÉS ET ARTICLES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2018175025A1

  公开（公告）日：2018-09-27

  The present disclosure provides a resin blend. The resin blend includes at least one diluent containing a single phthalonitrile functional group and at least one diphthalonitrile resin. Also provided are prepregs including the resin blend impregnated into continuous reinforcing fibers or a cloth. Similarly, the present disclosure provides a molding compound including chopped reinforcing fibers distributed in the resin blend. An article is also provided, which includes polymerization product of the resin blend. An alternative article includes a substrate and a layer of the resin blend disposed on the substrate. The diluent typically improves processability of the resin blend and lowers the softening temperature of the polymerization product of the resin blend.