Diphenyl-chlorfluorsilan | 312-39-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Diphenyl-chlorfluorsilan
• 英文别名: Diphenylchlorofluorosilane；chloro-fluoro-diphenylsilane
• CAS: 312-39-0
• 化学式: C₁₂H₁₀ClFSi
• 分子量: 236.748
• InChiKey: GOIHDYFWOQJRKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.45
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  Fluor-diphenylsilan 在 copper(l) iodide 、 copper dichloride 作用下， 以 乙醚 为溶剂， 以70%的产率得到Diphenyl-chlorfluorsilan
  参考文献：
  名称：

  Selective synthesis of halosilanes from hydrosilanes and utilization for organic synthesis

  摘要：

  Selective synthesis of halosilanes has been examined. Various types of halosilanes and halohydrosilanes, such as R3SiX, R2SiHX, R2SiX2, RSiH2X, RSiHX2 (X = Cl, Br, F), were obtained by the reactions of the corresponding hydrosilanes with Cu(II)-based reagents selectively in high yields. This method could be also applied to the synthesis of chlorofluorosilanes and chlorohydrogermanes. On the other hand, iodo- and bromosilanes and germanes were obtained by Pd- or Ni-catalyzed hydride-halogen exchange reactions of hydrosilanes with alkyl or allyl halides. Their synthetic applications have been demonstrated by using iodo-and bromosilanes and chlorofluorosilanes. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00254-7

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 58, page 165 - 167
  作者：

  DOI：——

  日期：——
• Organofluorosilanes and method of making same
  申请人：DOW CHEMICAL CO

  公开号：US02436777A1

  公开（公告）日：1948-02-24