copper;N-oxido-N-phenylnitrous amide | 52079-21-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: copper;N-oxido-N-phenylnitrous amide
• CAS: 52079-21-7
• 化学式: C₁₂H₁₀CuN₄O₄
• 分子量: 337.782
• InChiKey: BGIDZELNQOHLNJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.34
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  112
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  copper;N-oxido-N-phenylnitrous amide 在 pyridine 作用下， 生成 Ni(ON(NO)Ph)2(pyridine)
  参考文献：
  名称：

  Charalambous, John; Haines, L. Ian B.; Harris, Nigel J., Journal of Chemical Research - Part S

  摘要：

  DOI：
• 作为产物：
  描述：

  copper(II) oxide 在 Mg 、 NO 、 phenyl halide 作用下， 以 乙醚 、 水 为溶剂， 生成 copper;N-oxido-N-phenylnitrous amide
  参考文献：
  名称：

  N-亚硝基-N-烷基羟胺的铜（II）和铁（III）配合物，以及双（N-亚硝基-N-异丙基羟丙基氨基）铜和三（N-亚硝基-N-）的X射线晶体结构丙基羟基laminato）铁（III）

  摘要：

  摘要通过将一氧化氮与格氏试剂反应得到的混合物水解，制备了N-亚硝基-N-烷基羟胺，并将其稳定为铜（II）或铁（III）配合物Cu（RN2O2）2和Fe（RN2O2） ）3，其中R是例如Me，Et，Pri，Buiso，Ph，n-C8H17或n-C12H25。该复合物已通过分析，磁性和光谱测量表征。通过单晶X射线方法，发现Cu（PriN2O2）2是反平面的，而Fe（PrnN2O2）3具有面部八面体的结构。在每个络合物中，NO键长相等，铜和铁络合物之间无明显变化。

  DOI：

  10.1016/s0277-5387(00)80898-0

文献信息

• COPPER AND/OR COPPER OXIDE DISPERSION, AND ELECTROCONDUCTIVE FILM FORMED USING DISPERSION
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP3026677A1

  公开（公告）日：2016-06-01

  To provide a copper and/or copper oxide dispersion capable of forming an electroconductive film exhibiting excellent stability with respect to temporal change and having a fine pattern form, an electroconductive film laminate obtained by laminating the electroconductive film produced using the copper and/or copper oxide dispersion, and an electroconductive film transistor. The copper and/or copper oxide dispersion contains 0.50-60 mass% of copper and/or copper oxide microparticles and the following components (1)-(4): (1) a surface energy modifier; (2) an organic compound having a phosphate group; (3) 0.050-10 mass% of a solvent having a vapor pressure of 0.010 Pa to less than 20 Pa at 20°C; and (4) a solvent having a vapor pressure of 20 Pa to 150 hPa at 20°C. The electroconductive laminate is obtained by laminating an electroconductive film containing copper on a substrate.

  提供一种能够形成导电膜的铜和/或氧化铜分散体，该导电膜在时间变化方面表现出优异的稳定性，并具有精细的图案形状；提供一种通过层压使用该铜和/或氧化铜分散体生产的导电膜而获得的导电膜层压板；以及一种导电膜晶体管。铜和/或氧化铜分散液含有 0.50-60 质量%的铜和/或氧化铜微粒以及以下成分 (1)-(4)：(1) 表面能改性剂；(2) 具有磷酸基团的有机化合物；(3) 0.050-10 质量%的溶剂，其在 20°C 时的蒸气压为 0.010 Pa 至小于 20 Pa；以及 (4) 一种溶剂，其在 20°C 时的蒸气压为 20 Pa 至 150 hPa。导电层压板是通过在基板上层压含有铜的导电薄膜而获得的。
• DISPERSION
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP3305853A1

  公开（公告）日：2018-04-11

  A dispersion which contains a dispersant and particles selected from among metal particles and metal oxide particles, and which is characterized in that: the dispersant has a chemical structure that is able to be bonded or adsorbed to the particles; and the dispersant contains a low-molecular-weight dispersant that has at least one peak within a molecular weight region of 31 or more but less than 1,000 in the molecular weight distribution curve in terms of polyethylene glycol as determined by gel permeation chromatography and a high-molecular-weight dispersant that has at least one peak within a molecular weight region of 1,000 or more but 40,000 or less in the above-described molecular weight distribution curve.

  一种分散剂，它含有一种分散剂和选自金属颗粒和金属氧化物颗粒的颗粒，其特征在于分散剂的化学结构能与颗粒结合或吸附；分散剂含有一种低分子量分散剂，该分散剂在凝胶渗透色谱法测定的聚乙二醇分子量分布曲线中，至少有一个峰值在 31 或以上但小于 1,000 的分子量区域内；还含有一种高分子量分散剂，该分散剂在上述分子量分布曲线中，至少有一个峰值在 1,000 或以上但小于 40,000 的分子量区域内。
• Copper and/or copper oxide dispersion, and electroconductive film formed using dispersion
  申请人：ASAHI KASEI KABUSHIKI KAISHA

  公开号：US10424648B2

  公开（公告）日：2019-09-24

  To provide a copper and/or copper oxide dispersion capable of forming an electroconductive film exhibiting excellent stability with respect to temporal change and having a fine pattern form, an electroconductive film laminate obtained by laminating the electroconductive film produced using the copper and/or copper oxide dispersion, and an electroconductive film transistor. The copper and/or copper oxide dispersion contains 0.50-60 mass % of copper and/or copper oxide microparticies and the following components (1)-(4): (1) a surface energy modifier; (2) an organic compound having a phosphate group; (3) 0.050-10 mass % of a solvent having a vapor pressure of 0.010 Pa to less than 20 Pa at 20° C.; and (4) a solvent having a vapor pressure of 20 Pa to 150 hPa at 20° C. The electroconductive laminate is obtained by laminating an electroconductive film containing copper on a substrate.

  提供一种能够形成导电薄膜的铜和/或氧化铜分散体，该导电薄膜在时间变化方面表现出优异的稳定性，并具有精细的图案形状；提供一种通过层压使用该铜和/或氧化铜分散体生产的导电薄膜而获得的导电薄膜层压板；以及一种导电薄膜晶体管。铜和/或氧化铜分散液含有 0.50-60 质量％的铜和/或氧化铜微颗粒和以下成分 (1)-(4)：(1) 表面能改性剂；(2) 具有磷酸基团的有机化合物；(3) 0.0.010 Pa 至小于 20 Pa（20°C 时）的溶剂；以及 (4) 20 Pa 至 150 hPa（20°C 时）的溶剂。
• Metal oxide dispersion
  申请人：Maruyama Mutsuhiro

  公开号：US20050069648A1

  公开（公告）日：2005-03-31

  The present invention relates to a metal oxide dispersion, which can form a metal thin film onto a substrate by heat treatment at a low temperature, wherein a metal oxide having a particle diameter of less than 200 nm is dispersed in the dispersion medium. By heat treating the dispersion after applying it onto a substrate, a metal thin film is formed.

  本发明涉及一种金属氧化物分散液，它可以通过低温热处理在基底上形成金属薄膜，其中颗粒直径小于 200 nm 的金属氧化物分散在分散介质中。将分散液涂抹在基底上后，通过热处理形成金属薄膜。
• Bis(cupferronato)copper(II), [Cu(C6H5N2O2)2]
  作者：Y. Elerman、O. Atakol、I. Svoboda、M. Geselle

  DOI：10.1107/s0108270195002770

  日期：1995.8.15

  The Cu atom in the title molecule, bis(N-nitroso-N- phenylhydroxylaminato-O,O')copper(II), is coordinated by four donor atoms to a planar, almost square coordination geometry. The O1-Cu-O2 and O1-Cu-O2A angles are 81.77(9) and 98.23(9)degrees, respectively, and the Cu1-O1 and Cu1-O2 bond lengths are 1.902(2) and 1.892(2) Angstrom, respectively.