1.3-Bis-allylmercapto-propan | 822-00-4

• 分子结构分类: 有机化合物
• 英文名称: 1.3-Bis-allylmercapto-propan
• 英文别名: 1,3-bis-allylsulfanyl-propane；3,3'-propane-1,3-diylbissulfanyl-bis-propene；4,8-dithiaundeca-1,10-diene；1,3-Bis(prop-2-enylsulfanyl)propane
• CAS: 822-00-4
• 化学式: C₉H₁₆S₂
• 分子量: 188.358
• InChiKey: GYEMMEGOKFCXCD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  11
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1,3-丙二硫醇 、 烯丙醇 在 [Ru(Cp*)(η³-C3H5)(CH3CN)2](PF6)2 作用下， 以 氘代乙腈 为溶剂， 反应 20.0h， 生成 1.3-Bis-allylmercapto-propan
  参考文献：
  名称：

  以烯丙醇为底物快速钌催化的巯基烯丙基化

  摘要：

  绿色快速：通过使用烯丙醇作为底物，芳香和脂肪族硫醇的烯丙基化在室温下使用Ru催化剂仅需数分钟（见方案）。定量转化是正常的，该催化剂具有较高的官能团耐受性。

  DOI：

  10.1002/chem.200900192

文献信息

• ALLYL SULFIDE COMPOUNDS, AND COMPOSITIONS AND METHODS USING SAID COMPOUNDS FOR REPELLING BLOOD-FEEDING ARTHROPODS
  申请人：Contech Enterprises Inc.

  公开号：EP2142500B1

  公开（公告）日：2013-07-31
• COMPOUNDS, COMPOSITIONS AND METHODS FOR REPELLING BLOOD-FEEDING ARTHROPODS AND DETERRING THEIR LANDING AND FEEDING
  申请人：GRIES Regine M.

  公开号：US20090069407A1

  公开（公告）日：2009-03-12

  This invention relates to compositions of one or more compounds that incorporate one or more allyl sulfide, allyl disulfide or allyl polysulfide moieties, or one or more allyl sulfide, allyl disulfide or allyl polysulfide moieties and one or more hydroxyl groups, used in effective amount in formulations, including emulsions, to repel blood-feeding ectoparasitic arthropods, including mosquitoes, and to deter them from landing and feeding when applied to the skin, clothing or environment of animals, including humans. Said compounds can include, but are not limited to, 8-allyl-sulfanyloctan-1-ol. This invention also relates to compositions comprising one or more of said compounds in further combination with other arthropod repellent and deterrent compounds, including vanillin. These compounds may be formulated with inert ingredients to form a liquid, gel, paste, soap, spray, aerosol or powder.
• US8889731B2
  申请人：——

  公开号：US8889731B2

  公开（公告）日：2014-11-18
• [EN] ALLYL SULFIDE COMPOUNDS, AND COMPOSITIONS AND METHODS USING SAID COMPOUNDS FOR REPELLING BLOOD-FEEDING ARTHROPODS<br/>[FR] COMPOSÉS SULFURES D'ALLYLE, ET COMPOSITIONS ET PROCÉDÉS UTILISANT LESDITS COMPOSÉS POUR REPOUSSER LES ARTHROPODES HÉMATOPHAGES
  申请人：PHERO TECH INTERNAT INC

  公开号：WO2008116321A1

  公开（公告）日：2008-10-02

  [EN] This invention relates to compositions of one or more compounds that incorporate one or more allyl sulfide, allyl disulfide or allyl polysulfide moieties, or one or more allyl sulfide, allyl disulfide or allyl polysulfide moieties and one or more hydroxyl groups, used in effective amount in formulations, including emulsions, to repel blood-feeding ectoparasitic arthropods, including mosquitoes, and to deter them from landing and feeding when applied to the skin, clothing or environment of animals, including humans. Said compounds can include, but are not limited to, 8-allyl-sulfanyloctan-1-ol. This invention also relates to compositions comprising one or more of said compounds in further combination with other arthropod repellent and deterrent compounds, including vanillin. These compounds may be formulated with inert ingredients to form a liquid, gel, paste, soap, spray, aerosol or powder.
  [FR] La présente invention concerne des compositions d'un ou des composés qui incorporent un ou des groupements sulfure d'allyle, disulfure d'allyle ou polysulfure d'allyle, ou un ou des groupements sulfure d'allyle, disulfure d'allyle ou polysulfure d'allyle et un ou des groupes hydroxyle, utilisés en une quantité efficace dans des formulations, comprenant les émulsions, pour repousser les arthropodes ectoparasitiques hématophages, comprenant les moustiques, et pour les dissuader de se poser et de se nourrir lorsqu'ils sont sur la peau, les vêtements ou l'environnement d'animaux, y compris les humains. Lesdits composés peuvent comprendre, mais ne sont pas limités à, le 8-allyl-sulfanyloctan-1-ol. L'invention concerne également des compositions comprenant un ou plusieurs desdits composés également en combinaison avec d'autres composés répulsifs et dissuasifs contre les arthropodes, comprenant la vanilline. Ces composés peuvent être formulés avec des ingrédients inertes afin de former un liquide, un gel, une pâte, un savon, un spray, un aérosol ou une poudre.