3,6-Di-tert-butyl-1,4-dimethyl-1H,4H-pyrrolo[3,2-b]pyrrole-2,5-dione | 104944-00-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 3,6-Di-tert-butyl-1,4-dimethyl-1H,4H-pyrrolo[3,2-b]pyrrole-2,5-dione
• 英文别名: 3,6-Ditert-butyl-1,4-dimethylpyrrolo[3,2-b]pyrrole-2,5-dione
• CAS: 104944-00-5
• 化学式: C₁₆H₂₄N₂O₂
• 分子量: 276.379
• InChiKey: DVSKQYHQQPQKFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,6-di-t-butyl-2,5-dioxo-1,4-dihydropyrrolo<3,2-b>pyrrole 、 碘甲烷 在 sodium hydride 作用下， 以 1,4-二氧六环 为溶剂， 反应 3.0h， 以80%的产率得到3,6-Di-tert-butyl-1,4-dimethyl-1H,4H-pyrrolo[3,2-b]pyrrole-2,5-dione
  参考文献：
  名称：

  SYNTHESIS AND PROPERTIES OF 1,4-DIHYDROPYRROLO[3,2-b]PYRROLE-2,5-DIONE DERIVATIVES

  摘要：

  本文介绍了一种研究 1,4-二氢吡咯并[3,2-b]吡咯-2,5-二酮衍生物的新方法，这些衍生物被认为属于一种有趣的氧化还原体系。文中介绍了这些衍生物的还原电位以及化学和光谱特性，还讨论了它们作为电子受体的能力。

  DOI：

  10.1246/cl.1985.1809

文献信息

• Bithiophene Sulfonamide-Based Molecular and Polymeric Semiconductors
  申请人：Northwestern University

  公开号：US20160149138A1

  公开（公告）日：2016-05-26

  The present invention relates to new semiconducting compounds having at least one optionally substituted bithiophene sulfonamide moiety. The compounds disclosed herein can exhibit high carrier mobility and/or efficient light absorption/emission characteristics, and can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.

  本发明涉及具有至少一个可选择取代的双噻吩磺酰胺基团的新半导体化合物。本文所披露的化合物可以表现出高载流子迁移率和/或高效的光吸收/发射特性，并且具有一定的加工优势，如可溶性加工性和/或在常温下良好的稳定性。
• ORGANIC SEMICONDUCTING COMPOUNDS AND RELATED OPTOELECTRONIC DEVICES
  申请人：Polyera Corporation

  公开号：US20170104160A1

  公开（公告）日：2017-04-13

  The present teachings relate to new organic semiconducting compounds and their use as active materials in organic and hybrid optical, optoelectronic, and/or electronic devices such as photovoltaic cells, light emitting diodes, light emitting transistors, and field effect transistors. The present compounds can provide improved device performance, for example, as measured by power conversion efficiency, fill factor, open circuit voltage, field-effect mobility, on/off current ratios, and/or air stability when used in photovoltaic cells or transistors. The present compounds can have good solubility in common solvents enabling device fabrication via solution processes.

  本教学涉及新的有机半导体化合物及其在有机和混合光学、光电子和/或电子器件中作为活性材料的用途，如光伏电池、发光二极管、发光晶体管和场效应晶体管。这些化合物可以提供改进的器件性能，例如通过光电转换效率、填充因子、开路电压、场效应迁移率、开/关电流比以及在光伏电池或晶体管中使用时的空气稳定性等指标来衡量。这些化合物在常见溶剂中具有良好的溶解性，可以通过溶液工艺进行器件制备。
• Semiconducting Compounds and Related Devices
  申请人：Polyera Corporation

  公开号：US20170110666A1

  公开（公告）日：2017-04-20

  The present teachings relate to new semiconducting compounds including one or more moieties represented by formula (I): wherein X is a chalcogen; and one or more linear conjugated moieties and/or one or more cyclic conjugated moieties other than the moieties represented by formula (I). The present compounds can be used to prepare thin film semiconductor components which can be incorporated into various electronic, optical, and optoelectronic devices.

  本教学涉及新的半导体化合物，其中包括一个或多个由公式（I）表示的基团，其中X是硫族元素; 以及一个或多个线性共轭基团和/或一个或多个不同于公式（I）所表示的基团的环状共轭基团。这些化合物可以用于制备薄膜半导体元件，这些元件可以集成到各种电子、光学和光电器件中。
• MUKAI, TOSHIO;KONNO, AKINORI;KUMAGAI, TSUTOMU;SATAKE, KYOSUKE, CHEM. LETT., 1985, N 12, 1809-1812
  作者：MUKAI, TOSHIO、KONNO, AKINORI、KUMAGAI, TSUTOMU、SATAKE, KYOSUKE

  DOI：——

  日期：——
• Phenazine-Based Molecular and Polymeric Semiconductors
  申请人：Universita degli Studi di Milano - Bicocca

  公开号：US20160351815A1

  公开（公告）日：2016-12-01

  The present invention relates to new semiconducting compounds having at least one optionally substituted phenazine moiety. The compounds disclosed herein can exhibit high carrier mobility and/or efficient light absorption/emission characteristics, and can possess certain processing advantages such as solution-processability and/or good stability at ambient conditions.