2,2'-(Pyrene-2,7-diylidene)dipropanedinitrile | 64535-30-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 2,2'-(Pyrene-2,7-diylidene)dipropanedinitrile
• 英文别名: 2-[7-(dicyanomethylidene)pyren-2-ylidene]propanedinitrile
• CAS: 64535-30-4
• 化学式: C₂₂H₈N₄
• 分子量: 328.3
• InChiKey: BVEDIAXLKAYGFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  95.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,2'-(2,7-pyrenediyl)bis 生成 2,2'-(Pyrene-2,7-diylidene)dipropanedinitrile
  参考文献：
  名称：

  ACTON, N.;HOU, D.;SCHWARZ, J.;KATZ, T. J., J. ORG. CHEM., 1982, 47, N 6, 1011-1018

  摘要：

  DOI：

文献信息

• Dibenzoborole-based compound and organic light emitting device including the same
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10236453B2

  公开（公告）日：2019-03-19

  A dibenzoborole-based compound and an organic light-emitting device including the same. The dibenzoborole-based compound is represented by the formula A1-(A2)n1, wherein A1 may be selected from specific aromatic and non-aromatic carbocycles and heterocycles, n1 may be an integer selected from 1 to 10, and each A2 moiety may independently be selected from a group represented by Formula 2: The dibenzoborole-based compound may be included in the hole transport region or hole transport layer. When the dibenzoborole-based compound has strong electron acceptor characteristics, the hole injection barrier between the anode and the organic layer may be reduced, and thus, an organic light-emitting device including the dibenzoborole-based compound may have high efficiency and a long lifespan.

  一种二苯并硼基化合物和包括该化合物的有机发光器件。二苯并硼基化合物由式 A1-(A2)n1 表示，其中 A1 可以选自特定的芳香族和非芳香族碳环和杂环，n1 可以是选自 1 到 10 的整数，每个 A2 分子可以独立地选自式 2 所代表的基团： 二苯并硼基化合物可包含在空穴传输区域或空穴传输层中。当二苯并硼基化合物具有较强的电子受体特性时，阳极和有机层之间的空穴注入势垒可以降低，因此，包含二苯并硼基化合物的有机发光器件可以具有较高的效率和较长的使用寿命。
• Organic light-emitting device
  申请人：Samsung Electronics Co., Ltd.

  公开号：US10741772B2

  公开（公告）日：2020-08-11

  An organic light-emitting device (OLED) includes a first electrode, a second electrode, an emission layer between the first electrode and the second electrode and including an electron-transporting host and a hole-transporting host, a hole transport region between the first electrode and the emission layer and including a hole transport layer, and an electron transport region between the emission layer and the second electrode and including an electron transport layer, wherein the OLED satisfies Equations 1 and 2 below: 0.75 eV≤|LUMOH(ET)−LUMOH(HT)|≤0.90 eV   |E(S1,H(ET))−E(S1,H(HT))|<0.15 eV   wherein in Equations 1 and 2, LUMOH(ET) refers to a lowest unoccupied molecular orbital (LUMO) energy level of the electron-transporting host, LUMOH(HT) refers to an LUMO energy level of the hole-transporting host, E(S1, H(ET)) refers to a singlet energy level of the electron-transporting host, and E(S1, H(HT)) refers to a singlet energy level of the hole-transporting host.

  一种有机发光器件（OLED）包括第一电极、第二电极、第一电极和第二电极之间的发射层（包括电子传输宿主和空穴传输宿主）、第一电极和发射层之间的空穴传输区域（包括空穴传输层）以及发射层和第二电极之间的电子传输区域（包括电子传输层），其中 OLED 满足以下公式 1 和 2： 0.75 eV≤|LUMOH(ET)-LUMOH(HT)|≤0.90 eV |E(S1,H(ET))-E(S1,H(HT))| 其中等式 1 和 2 中，LUMOH(ET) 指电子传输宿主的最低未占分子轨道 (LUMO) 能级，LUMOH(HT) 指空穴传输宿主的 LUMO 能级，E(S1, H(ET)) 指电子传输宿主的单电子能级，E(S1, H(HT)) 指空穴传输宿主的单电子能级。
• MAXFIELD M.; WILLI S. M.; COWAN D. O.; BLOCH A. N.; POEHLER T. O., J. CHEM. SOC. CHEM. COMMUN., 1980, NO 20, 947-948
  作者：MAXFIELD M.、 WILLI S. M.、 COWAN D. O.、 BLOCH A. N.、 POEHLER T. O.

  DOI：——

  日期：——
• HYBRID AND/OR COMPLEX MATERIAL, PHOTOELECTRIC CONVERSION MATERIAL, DYE-SENSITIZED SOLAR CELL, DYE-SENSITIZED SOLAR CELL DEVICE, MANUFACTURING METHOD OF PHOTOELECTRIC CONVERSION DEVICE, AND METHOD OF ANALYZING TITANIUM OXIDE CRYSTAL STRUCTURE
  申请人：Segawa Hiroshi

  公开号：US20110011459A1

  公开（公告）日：2011-01-20

  There is provided a hybrid and/or complex material or the like which can realize a high-efficient photoelectric conversion material or the like. One aspect of the present invention lies in a dye-sensitized solar cell device 10 , characterized by including: a first substrate 11 ; a first conductive layer 12 formed on the first substrate; a Pt catalyst layer formed on the first conductive layer; an electrolyte layer 13 formed on the Pt catalyst layer; a dye-adsorbed metal oxide layer 14 formed on the electrolyte layer in which 7,7,8,8-tetracyanoquinodimethane is adsorbed to an anatase type titanium oxide; a second conductive layer 15 formed on the dye-adsorbed metal oxide layer; and a second substrate 16 formed on the second conductive layer. According to this composition above, there is obtained a high-efficient dye-sensitized solar cell device in which light can be converted efficiently over wide wavelengths.
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20160072078A1

  公开（公告）日：2016-03-10

  An organic light-emitting device (OLED) includes a first electrode, a second electrode, an emission layer between the first electrode and the second electrode and including an electron-transporting host and a hole-transporting host, a hole transport region between the first electrode and the emission layer and including a hole transport layer, and an electron transport region between the emission layer and the second electrode and including an electron transport layer, wherein the OLED satisfies Equations 1 and 2 below: 0.75 eV≦| LUMO H(ET) −LUMO H(HT) |≦0.90 eV   | E ( S 1,H(ET) )− E ( S 1,H(HT) )|<0.15 eV   wherein in Equations 1 and 2, LUMO H(ET) refers to a lowest unoccupied molecular orbital (LUMO) energy level of the electron-transporting host, LUMO H(HT) refers to an LUMO energy level of the hole-transporting host, E(S 1, H(ET) ) refers to a singlet energy level of the electron-transporting host, and E(S 1, H(HT) ) refers to a singlet energy level of the hole-transporting host.