cis-(Et3P)2Pt(Cl)(Z-CHCH-cyclo-C3HPh2) | 479420-72-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cis-(Et3P)2Pt(Cl)(Z-CHCH-cyclo-C3HPh2)
• 英文别名: (3-ethenyl-2-phenylcyclopropen-1-yl)benzene;platinum(2+);triethylphosphane;chloride
• CAS: 479420-72-9
• 化学式: C₂₉H₄₃ClP₂Pt
• 分子量: 684.141
• InChiKey: UJMMJCVBGHSCQB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  9.96
• 重原子数：
  33
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  thallium(I) hexafluorophosphate 、 cis-(Et3P)2Pt(Cl)(Z-CHCH-cyclo-C3HPh2) 以 四氢呋喃 为溶剂， 以86%的产率得到[(η3-C5H3Ph2)Pt(PEt3)2]PF6
  参考文献：
  名称：

  Rearrangement of a σ-2-(Cycloprop-2-enyl)vinyl- to an η³-Cyclopentadienylplatinum(II) Complex. Selective Protonolysis of the Platinum−Methyl Bond

  摘要：

  The sigma-2-(cycloprop-2-enyl)vinylplatinum(II) complex (PEt3)(2)Pt(Me)(CH=CH-cyclo-C3HPh2) (5) was prepared and characterized by NMR spectroscopy and X-ray crystallography. Treatment of 5 with Bronsted acids results in selective splitting of the Pt-methyl bond to give chloro derivative (PEt3)(2)Pt(Cl)(CH=CH-cyclo-C3HPh2) (6), or the rearranged eta(3)-diphenylcyclopentadienyl cation 7(+), depending on the acid employed. Formation of cation 7(+) could also be accomplished by treatment of 6 with TIPF6. Monitoring the protonolysis reactions by NMR spectroscopy at -60 degreesC, however, showed no evidence for platinabenzene or platinabenzvalene intermediates.

  DOI：

  10.1021/om0206507
• 作为产物：
  描述：

  (Z)-(3-(2-iodovinyl)cycloprop-1-ene-1,2-diyl)dibenzene 在 BuLi 作用下， 以 甲醇 、 乙醚 为溶剂， 生成 cis-(Et3P)2Pt(Cl)(Z-CHCH-cyclo-C3HPh2)
  参考文献：
  名称：

  Rearrangement of a σ-2-(Cycloprop-2-enyl)vinyl- to an η³-Cyclopentadienylplatinum(II) Complex. Selective Protonolysis of the Platinum−Methyl Bond

  摘要：

  The sigma-2-(cycloprop-2-enyl)vinylplatinum(II) complex (PEt3)(2)Pt(Me)(CH=CH-cyclo-C3HPh2) (5) was prepared and characterized by NMR spectroscopy and X-ray crystallography. Treatment of 5 with Bronsted acids results in selective splitting of the Pt-methyl bond to give chloro derivative (PEt3)(2)Pt(Cl)(CH=CH-cyclo-C3HPh2) (6), or the rearranged eta(3)-diphenylcyclopentadienyl cation 7(+), depending on the acid employed. Formation of cation 7(+) could also be accomplished by treatment of 6 with TIPF6. Monitoring the protonolysis reactions by NMR spectroscopy at -60 degreesC, however, showed no evidence for platinabenzene or platinabenzvalene intermediates.

  DOI：

  10.1021/om0206507