3,6-dichloro-o-benzenedicarbonitrile | 56732-42-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,6-dichloro-o-benzenedicarbonitrile
• 英文别名: 3,6-Dichlorophthalonitrile；3,6-dichlorobenzene-1,2-dicarbonitrile
• CAS: 56732-42-4
• 化学式: C₈H₂Cl₂N₂
• 分子量: 197.023
• InChiKey: RSKSHEHZUXLZHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3,6-dichlorophthalamide 在 吡啶 、 三氯氧磷 作用下， 反应 1.5h， 生成 3,6-dichloro-o-benzenedicarbonitrile
  参考文献：
  名称：

  [EN] PHTHALOCYANINES AND THEIR USE IN INK-JET PRINTING
  [FR] PHTALOCYANINES ET LEUR UTILISATION EN IMPRESSION PAR JET D'ENCRE

  摘要：

  一种制备邻苯二甲酰亚菲青或金属邻苯二甲酰亚菲青染料及其盐的混合物的方法，包括将化合物式（1）与化合物式（2）和/或化合物式（3）环化：其中：R1是烃基团；R2是H或烃基团；R3是H，可选择地取代的烷基，可选择地取代的芳基或可选择地取代的杂环烷基；R4和R5是氰基，羧基，羧酰胺基或共同形成式（a）的基团；X是电子吸引基团；n为1至4：其中环化过程在适当的氮源（如果需要）和金属盐（如果需要）的存在下进行。此外，还涉及新化合物、墨水、印刷工艺、印刷材料（包括彩色滤光片）和喷墨墨盒。

  公开号：

  WO2010146381A1

文献信息

• METHOD FOR PRODUCING A PIGMENT
  申请人：Nakahama Kazumichi

  公开号：US20080182984A1

  公开（公告）日：2008-07-31

  Provided is a method for producing a pigment, in particular, a metal phthalocyanine, in high yield and in a green process. The method has (1) a step of obtaining a solution mixture by mixing at least one type of compound serving as a raw material for a pigment with a solvent, and (2) a step of obtaining the pigment by reacting the compound while holding the solution mixture at not less than a temperature where a subcritical state or a supercritical state of the solvent occurs.

  提供了一种高产且绿色的生产颜料的方法，特别是金属菲托氰颜料的方法。该方法包括(1)通过将至少一种化合物与溶剂混合得到溶液混合物的步骤，以及(2)在保持溶液混合物处于亚临界态或超临界态的温度不低于时反应该化合物以得到颜料的步骤。
• Phthalocyanines and Their Use in Ink-Jet Printing
  申请人：Dunwoody Patricia Mary

  公开号：US20120081482A1

  公开（公告）日：2012-04-05

  A process for preparing a mixture of phthalocyanine or metallo-phthalocyanine dyes and salts thereof which comprises cyclisation of a compound of Formula (1) with a compound of Formula (2) and/or Formula (3): wherein: R 1 is a hydrocarbyl group; R 2 is H or a hydrocarbyl group; R 3 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted heterocyclyl; R 4 and R 5 are cyano, carboxy carboxamide or together form a group of formula X is an electron withdrawing group; and n is 1 to 4: wherein the cyclisation process is carried out in the presence of a suitable nitrogen source (if required) and a metal salt (if required). Also novel compounds, inks, printing processes, printed materials (including color filters) and ink jet cartridges.

  一种制备酞菁或金属酞菁染料及其盐的混合物的方法，包括将式（1）化合物与式（2）和/或式（3）化合物环化反应：其中：R1是烃基；R2是氢或烃基；R3是氢、可选取代烷基、可选取代芳基或可选取代杂环基；R4和R5是氰基、羧基羧酰胺基或共同形成公式的基团X是电子提取基团；n为1至4：其中环化过程在适当的氮源（如果需要）和金属盐（如果需要）的存在下进行。此外还提供了新的化合物、墨水、印刷工艺、印刷材料（包括彩色滤光片）和喷墨墨盒。
• Organic fluorine compounds
  申请人：Nippon Shokubai Kagaku Kogyo Co., Ltd

  公开号：EP0120575A1

  公开（公告）日：1984-10-03

  Compounds such as pentafluorobenzonitrile, tetra- fluorophthalonitriles, and pentafluoropyridine are produced by halogen exchange with a chloro- or bromo-organic compound fluorinating agent such as an alkali metal fluoride using benzonitrile as a solvent as from 190° to 400°C.

  五氟苯腈、四氟邻苯二甲酰腈和五氟吡啶等化合物是以苯甲腈为溶剂，通过与氯或溴有机化合物氟化剂（如碱金属氟化物）在 190° 至 400°C 温度范围内进行卤素交换而制得的。
• Method for production of organic fluorine compound
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0899256A2

  公开（公告）日：1999-03-03

  A method for the production of an aromatic fluorine compound is provided which is capable of preventing the occurrence of benzoic acid fluorides during the course of a halogenation exchange reaction or allowing removal of the benzoic acid fluorides formed at all. A method for the production of an organic fluorine compound is disclosed which comprises preventing the occurrence of acid fluorides of an aromatic compound during the production of the organic fluorine compound by the reaction of an organic chlorine or bromine compound with a fluorinating agent in benzonitrile as a solvent or allowing removal of the acid fluorides formed.

  本发明提供了一种生产芳香族含氟化合物的方法，该方法能够防止在卤化交换反应过程中出现苯甲酸氟化物，或能够从根本上去除所形成的苯甲酸氟化物。本发明公开了一种生产有机氟化合物的方法，该方法包括在生产有机氟化合物的过程中，通过有机氯或溴化合物与氟化剂在苯甲腈作为溶剂中的反应，防止出现芳香族化合物的酸性氟化物，或允许去除形成的酸性氟化物。
• Trifluorovinyloxy monomers and polymers
  申请人：Moore Roger David

  公开号：US20070238856A1

  公开（公告）日：2007-10-11

  Reactive monomers containing the trifluorovinyloxy group may be copolymerized to form polymers useful as membranes, especially polymer electrolyte membranes for fuel cells. The monomers have the formula ((CF 2 CFO(R 1 ) p ) n ArX 2 wherein Ar is a trivalent, tetravalent or pentavalent, substituted or unsubstituted, aromatic or heteroaromatic, monocyclic or polycyclic group having from 5 to 50 carbon atoms; X is OH, SH, NR 2a R 2b , F or Br; p is 0 or 1; n is 1, 2 or 3; R 1 is substituted or unsubstituted phenyl and R 2a and R 2b are independently H, C 1 -C 8 alkyl or C 1 -C 8 perfluoroalkyl.