[(2,2'-bipyridyl)Pd(CH3)(Tol(H)C=NPh)]OTf | 200642-01-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [(2,2'-bipyridyl)Pd(CH3)(Tol(H)C=NPh)]OTf
• 英文别名: carbanide;1-(4-methylphenyl)-N-phenylmethanimine;palladium(2+);2-pyridin-2-ylpyridine;trifluoromethanesulfonate
• CAS: 200642-01-9
• 化学式: CF₃O₃S*CH₃*C₁₀H₈N₂*C₁₄H₁₃N*Pd
• 分子量: 621.976
• InChiKey: LWQDINCAMZMXOF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  6.39
• 重原子数：
  37
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  104
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  [(2,2'-bipyridyl)Pd(CH3)(Tol(H)C=NPh)]OTf 、 一氧化碳 以 二氯甲烷 为溶剂， 生成 [(2,2'-bipyridyl)Pd(COCH3)(Tol(H)C=NPh)]OTf
  参考文献：
  名称：

  Ring-Opening Polymerization of Heterocycles with Palladium Insertion Catalysts:  Observation of a Multifunctional Polymerization Initiator

  摘要：

  The palladium insertion polymerization catalysts (bipy)Pd(CH3)L+OTf- have been found to mediate a second class of polymerization reaction: the ring-opening polymerization of heterocycles. Unlike traditional cationic ring-opening processes, this polymerization is found to proceed via an unusual series of metal-based reactions, including novel steps which allow the coupling of insertion monomers (CO and norbornene) with ring-opened polymers.

  DOI：

  10.1021/om990265q