2-(4-Methylphenyl)-2-sulfanylpropanoic acid | 201022-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(4-Methylphenyl)-2-sulfanylpropanoic acid
• CAS: 201022-65-3
• 化学式: C₁₀H₁₂O₂S
• 分子量: 196.27
• InChiKey: ZNBIBMLZWLAECI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  38.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(4-Methylphenyl)-2-sulfanylpropanoic acid 、 2(CH₃(CH₂)3)4N⁽¹⁺⁾*MoO₂(OOCC(S)(C₆H₄CH₃)CH₃)2^(2-)*2H₂O=((CH₃(CH₂)3)4N)2[MoO₂(OOCC(S)(C₆H₄CH₃)CH₃)2]*2H₂O 以 甲醇 为溶剂， 生成 MoO(OOCC(S)(C₆H₄CH₃)CH₃)2^(1-)
  参考文献：
  名称：

  Synthesis and characterization of molybdenum(VI)-dioxo complexes containing both coordinated thiolate and carboxylate groups. Reactions with their own free ligands

  摘要：

  The synthesis, characterization and spectroscopic properties of a group of Mo(VI) complexes having thiocarboxylate ligands of type [(MoO2)-O-VI(O2CC(S)MePh-X)(2)](2-) have been reported (X = H,p-Me,p-Cl). The peak potential for the Mo(VI) reduction increases according to the electron-donor ability of X (Me > H > Cl), Reaction of these Mo(VI) complexes with their own free ligands has been studied by ESR and UV-Vis spectroscopy, yielding the monomeric [(MoO)-O-V(O2CC(S)MePh-X)(2)](-) as unique complex products. The kinetic study of this oxidation reaction has also been investigated. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05725-3

文献信息

• JPS54100335A
  申请人：——

  公开号：JPS54100335A

  公开（公告）日：1979-08-08
• Synthesis and characterization of molybdenum(VI)-dioxo complexes containing both coordinated thiolate and carboxylate groups. Reactions with their own free ligands
  作者：Hong Li、Pedro Palanca、Vicent Sanz、M. Teresa Picher、Luis R. Domingo、Antonio Doménech、José-Vicente Folgado

  DOI：10.1016/s0020-1693(97)05725-3

  日期：1998.2

  The synthesis, characterization and spectroscopic properties of a group of Mo(VI) complexes having thiocarboxylate ligands of type [(MoO2)-O-VI(O2CC(S)MePh-X)(2)](2-) have been reported (X = H,p-Me,p-Cl). The peak potential for the Mo(VI) reduction increases according to the electron-donor ability of X (Me > H > Cl), Reaction of these Mo(VI) complexes with their own free ligands has been studied by ESR and UV-Vis spectroscopy, yielding the monomeric [(MoO)-O-V(O2CC(S)MePh-X)(2)](-) as unique complex products. The kinetic study of this oxidation reaction has also been investigated. (C) 1998 Elsevier Science S.A.