3,3'-dimethyl-4,4'-butylidene-di-phenol | 57863-99-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-dimethyl-4,4'-butylidene-di-phenol
• 英文别名: 3,3'-Dimethyl-4,4'-butyliden-di-phenol；1,1-Bis-(4-hydroxy-2-methyl-phenyl)-butan；4.4'-Dioxy-2.2'-dimethyl-α-propyl-diphenylmethan；4.4'-Butyliden-di-m-kresol；4-[1-(4-Hydroxy-2-methylphenyl)butyl]-3-methylphenol
• CAS: 57863-99-7
• 化学式: C₁₈H₂₂O₂
• 分子量: 270.371
• InChiKey: ZAXXHOXGLUXDMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,3'-dimethyl-4,4'-butylidene-di-phenol 在 盐酸 作用下， 生成 4-Butyl-m-kresol
  参考文献：
  名称：

  v.Braun, Justus Liebigs Annalen der Chemie, 1929, vol. 472, p. 34

  摘要：

  DOI：
• 作为产物：
  描述：

  正丁醛 、 间甲酚 在 盐酸 作用下， 生成 3,3'-dimethyl-4,4'-butylidene-di-phenol
  参考文献：
  名称：

  THE CONDENSATION OF CERTAIN PHENOLS WITH SOME ALIPHATIC ALDEHYDES¹

  摘要：

  DOI：

  10.1021/ja01350a027

文献信息

• Foam bandage
  申请人：Seton Company

  公开号：EP0230387A2

  公开（公告）日：1987-07-29

  A disposable bandage, and a process for manufacturing it, which is prepared from a single sheet or strip of liquid permeable, flexible thermoplastic hydrophilic foam. The process includes coating the entire surface of one side of a foam sheet or strip with a layer of porous pressure sensitive adhesive, optionally positioning wound release material in the area(s) of the sheet or strip intended for wound contact, covering the same side of the laminate with a suitable release liner and heat compressing the laminate except in the area of the laminate intended for wound contact. The foam bandage so produced includes both a resilient absorbent pad and thin but absorbent adhesive-coated tabs and is suitable for general use as a disposable dressing. When the optional wound release material is eliminated, the bandage has special utility as an occlusive dressing. As a further option, the bandage may have a moisture vapor permeable, moisture impermeable skin thereon, to provide a water- and bacteria-proof protective outer layer for the foam bandage.

  一种一次性绷带及其生产工艺，该绷带由单片或单条液体可渗透柔性热塑性亲水泡沫塑料制成。该工艺包括在泡沫塑料片材或带材一侧的整个表面涂上一层多孔压敏粘合剂，在片材或带材的伤口接触区域放置伤口剥离材料，在层压材料的同一侧覆盖合适的剥离衬垫，热压层压材料（伤口接触区域除外）。这样制成的泡沫绷带包括弹性吸收垫和薄而吸水性强的涂有粘合剂的标签，适合作为一次性敷料使用。如果去掉可选的伤口脱膜材料，这种绷带就可以作为闭塞性敷料使用。作为进一步的选择，绷带上可以有一层透湿、不透水的表皮，为泡沫绷带提供防水和防菌的保护外层。
• Cohesive dressing
  申请人：Seton Company

  公开号：EP0235949A1

  公开（公告）日：1987-09-09

  A cohesive dressing, and a process for manufacturing it, which is prepared as a single sheet of self-adherent flexible foam. The foam is self-adherent due to the incorporation therein, throughout the foam matrix itself, of a limited quantity of a pressure sensitive adhesive composition. The process for manufacturing the cohesive dressing includes admixing an aqueous polymeric dispersion with an aqueous pressure sensitive adhesive emulsion until each is substantially uniformly distributed throughout the admixture, and frothing, casting or otherwise forming, curing and drying the admixture. The admixture must be frothed and cured to form a foam layer which is self-adherent without demonstrating significant wound or skin adherence. The polymeric composition of the cohesive dressing is preferably a polyurethane, and the pressure sensitive adhesive component of the foam is preferably an acrylic adhesive composition. The foam sheet thus produced may be cut or formed into drapes, tapes or dressings having any desired size or shape.

  一种粘性敷料及其生产工艺，该敷料是以单片自粘柔性泡沫塑料的形式制备的。由于在整个泡沫基质中加入了一定量的压敏胶组合物，泡沫具有自粘性。制造粘性敷料的工艺包括将水性聚合物分散体与水性压敏粘合剂乳液混合，直到两者基本均匀地分布在整个混合物中，然后将混合物发泡、浇注或以其他方式成型、固化和干燥。混合物必须经过发泡和固化以形成泡沫层，该泡沫层具有自粘性，不会对伤口或皮肤产生明显的附着力。粘性敷料的聚合物成分最好是聚氨酯，泡沫的压敏胶成分最好是丙烯酸粘合剂成分。这样制成的泡沫板可切割或成型为具有任何所需尺寸或形状的帘布、胶带或敷料。
• Self-release foam laminate
  申请人：Seton Company

  公开号：EP0246723A2

  公开（公告）日：1987-11-25

  A method of mechanically frothing and casting an aqueous polyurethane dispersion yields a foam which, when rolled, wound or stacked, is self-releasing from the pressure sensitive adhesive layer co-cured therewith. The method includes admixing an aqueous ionic polyurethane dispersion with a stearate stabilizer and an optional aziridine crosslinking agent, frothing and casting the admixture, and co-curing the resultant foam sheet with a pressure sensitive adhesive layer. Before frothing, the polyurethane dispersion contains particles having an average size of less than one micron, and contains between 35 and 70 percent by weight of the polyurethane dispersion, between 13 and 50 percent by weight of a 33 percent by weight dispersion of a stearate salt, and up to 33 percent by weight of a polyfunctional aziridine. The foam produced from the frothed admixture provides a substrate with which an uncured pressure sensitive adhesive can firmly co-cure but to which the cured adhesive demonstrates readily removable adhesion. The laminate of the foam with a pressure sensitive adhesive thus provides either a medical dressing, or a general purpose tape for industrial use, which may be stacked or self-wound without release paper.

  一种对水性聚氨酯分散体进行机械发泡和浇注的方法可产生一种泡沫，该泡沫在卷绕、缠绕或堆叠时，可从与之共固化的压敏胶层中自释放。该方法包括将水性离子聚氨酯分散体与硬脂酸稳定剂和可选的氮丙啶交联剂混合，发泡和浇注混合物，并将所得泡沫板与压敏胶层共同固化。发泡前，聚氨酯分散体含有平均粒径小于一微米的颗粒，并含有重量百分比为 35% 至 70% 的聚氨酯分散体、重量百分比为 13% 至 50% 的硬脂酸盐分散体和重量百分比为 33% 的多官能团氮丙啶。由起泡的混合物产生的泡沫提供了一种基材，未固化的压敏胶可与之牢固地共同固化，但固化后的胶粘剂显示出易于去除的粘附性。因此，泡沫与压敏胶的层压可以提供医用敷料，也可以提供工业用的通用胶带，这种胶带可以堆叠或自行缠绕，而不需要离型纸。
• US3991139A
  申请人：——

  公开号：US3991139A

  公开（公告）日：1976-11-09
• US4332710A
  申请人：——

  公开号：US4332710A

  公开（公告）日：1982-06-01