Copper;4-phenyl-2,6-dipyridin-2-ylpyridine;diacetate | 1440373-90-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Copper;4-phenyl-2,6-dipyridin-2-ylpyridine;diacetate
• CAS: 1440373-90-9
• 化学式: C₂₅H₂₁CuN₃O₄
• 分子量: 491.005
• InChiKey: VWQDQWZEJWSGHX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.38
• 重原子数：
  33
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  119
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4'-苯基-2,2':6',2''-三联吡啶 、 copper(II) acetate monohydrate 以 水 为溶剂， 反应 0.5h， 生成 Copper;4-phenyl-2,6-dipyridin-2-ylpyridine;diacetate
  参考文献：
  名称：

  Facile synthesis of 5-substituted-1H-tetrazoles and 1-substituted-1H-tetrazoles catalyzed by recyclable 4′-phenyl-2,2′:6′,2″-terpyridine copper(II) complex immobilized onto activated multi-walled carbon nanotubes

  摘要：

  5-Substituted-1H-tetrazoles can conveniently be synthesized from the corresponding nitriles by reaction with NaN3 using the efficient and recyclable heterogeneous catalyst prepared by immobilization of copper(II) complex of 4'-phenyl-2,2':6',2 ''-terpyridine on activated multi-walled carbon nanotubes [AMWCNTs-O-Cu(II)-PhTPY]. Excellent results were obtained in each case affording the corresponding tetrazole adducts in good to excellent yields. In general, aromatic nitriles with electron-donating group could be accomplished as well as that with electron-withdrawing groups. By leaving out nitrile from the reaction and adding CH(OEt)(3) and amines bearing various substituents, 1-substituted-1H-tetrazoles formed in water in high yields. The reported protocols have the advantages of rapid assembly of a host of heterocyclic systems in high yields with the added advantage of recycling and reuse of the catalyst. (C) 2013 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.04.013