1-bromo-2,4,6-trifluoro-3-trifluoromethylbenzene | 844439-00-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-bromo-2,4,6-trifluoro-3-trifluoromethylbenzene
• 英文别名: 2-Bromo-1,3,5-trifluoro-4-(trifluoromethyl)benzene；2-bromo-1,3,5-trifluoro-4-(trifluoromethyl)benzene
• CAS: 844439-00-5
• 化学式: C₇HBrF₆
• 分子量: 278.979
• InChiKey: WXJUJSRSVAUNLE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  四氢呋喃 、 三氟化硼乙醚 、 1-bromo-2,4,6-trifluoro-3-trifluoromethylbenzene 在 lithium chloro-isopropyl-magnesium chloride 作用下， 以 四氢呋喃 为溶剂， 反应 17.0h， 生成
  参考文献：
  名称：

  Process of manufacturing surfactants and lubricants

  摘要：

  一种生产醇基乙氧基化表面活性剂或润滑剂的方法，包括在聚合催化剂的存在下，将低分子量引发剂与乙烯氧化物反应，所述低分子量引发剂具有名义羟基功能至少为1，所述聚合催化剂为具有一般式M(R1)1(R2)1(R3)1(R4)0或1的路易斯酸催化剂，其中M为硼、铝、铟、铋或铒，R1、R2和R3均包括相同的氟烷基取代苯基，可选的R4包括一个功能基团或功能聚合物基团。R1、R2和R3是相同的氟烷基取代苯基。该方法还包括在路易斯酸催化剂的存在下形成具有比低分子量引发剂的数均分子量更大的醇基乙氧基化表面活性剂或润滑剂。

  公开号：

  US11186683B2

文献信息

• Process of manufacturing polyols
  申请人：Dow Global Technologies LLC

  公开号：US11198760B2

  公开（公告）日：2021-12-14

  A method of producing a polyether polyol that includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R1, R2, and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. R1, R2, and R3 are the same fluoroalkyl-substituted phenyl group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.

  一种生产聚醚多元醇的方法，包括在聚合催化剂存在下，使低分子量引发剂与环氧乙烷反应，低分子量引发剂的平均分子量小于1,000克/摩尔，公称羟基官能度至少为2，聚合催化剂为通式为M(R1)1(R2)1(R3)1(R4)0或1的路易斯酸催化剂。其中，M 是硼、铝、铟、铋或铒，R1、R2 和 R3 各包括一个相同的氟烷基取代苯基，任选的 R4 包括一个官能团或官能团聚合物基团。R1、R2 和 R3 是相同的氟烷基取代苯基。该方法进一步包括在路易斯酸催化剂存在下形成平均分子量大于低分子量引发剂平均分子量的聚醚多元醇。
• PROCESS OF MANUFACTURING SURFACTANTS AND LUBRICANTS
  申请人：Northwestern University

  公开号：EP3681926A1

  公开（公告）日：2020-07-22
• PROCESS OF MANUFACTURING POLYOLS
  申请人：Northwestern University

  公开号：EP3681927A1

  公开（公告）日：2020-07-22
• [EN] PROCESS OF MANUFACTURING SURFACTANTS AND LUBRICANTS<br/>[FR] PROCÉDÉ DE PRODUCTION DE TENSIOACTIFS ET DE LUBRIFIANTS
  申请人：UNIV NORTHWESTERN

  公开号：WO2019055741A1

  公开（公告）日：2019-03-21

  A method of producing an alcohol ethoxylate surfactant or lubricant includes reacting a low molecular weight initiator with ethylene oxide in the presence of a polymerization catalyst, the low molecular weight initiator having a nominal hydroxyl functionality at least 1, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1, whereas M is boron, aluminum, indium, bismuth or erbium, R1, R2 and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. R1, R2, and R3 are the same fluoroalkyl-substituted phenyl group. The method further includes forming the alcohol ethoxylate surfactant or lubricant having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.
• [EN] PROCESS OF MANUFACTURING POLYOLS<br/>[FR] PROCÉDÉ DE FABRICATION DE POLYOLS
  申请人：UNIV NORTHWESTERN

  公开号：WO2019055725A1

  公开（公告）日：2019-03-21

  A method of producing a polyether polyol that includes reacting a low molecular weight initiator with one or more monomers in the presence of a polymerization catalyst, the low molecular weight initiator having a number average molecular weight of less than 1,000 g/mol and a nominal hydroxyl functionality at least 2, the one or more monomers including at least one selected from propylene oxide and butylene oxide, and the polymerization catalyst being a Lewis acid catalyst having the general formula M(R1)1(R2)1(R3)1(R4)0 or 1. Whereas, M is boron, aluminum, indium, bismuth or erbium, R1, R2, and R3 each includes a same fluoroalkyl-substituted phenyl group, and optional R4 includes a functional group or functional polymer group. The method further includes forming a polyether polyol having a number average molecular weight of greater than the number average molecular weight of the low molecular weight initiator in the presence of the Lewis acid catalyst.