3,5-二乙烯基苯甲醛 | 195967-44-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3,5-二乙烯基苯甲醛
• 中文别名: 苯(甲)醛,3,5-二乙烯基-(9CI)
• 英文名称: 3,5-Divinyl-benzaldehyde
• 英文别名: 3,5-Divinylbenzaldehyde；3,5-bis(ethenyl)benzaldehyde
• CAS: 195967-44-3
• 化学式: C₁₁H₁₀O
• 分子量: 158.2
• InChiKey: CTYVYLLRFAOSND-UHFFFAOYSA-N

物化性质

• 沸点：
  290.7±39.0 °C(Predicted)
• 密度：
  1.034±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3,5-二乙烯基苯甲醛 、 1-bromo-3,5-bis(3',5'-di-t-butylstyryl)benzene 在 palladium diacetate 、 四丁基溴化铵 、 potassium carbonate 作用下， 生成 3,5-bis[(E)-2-[3,5-bis[(E)-2-(3,5-ditert-butylphenyl)ethenyl]phenyl]ethenyl]benzaldehyde
  参考文献：
  名称：

  A Simple Orthogonal Approach to Poly(phenylenevinylene) Dendrimers

  摘要：

  DOI：

  10.1021/ja971790o

文献信息

• Synthesis of Oligoquinoline Dendronized Fullerenes for Potential Use in Organic Photovoltaic Devices
  作者：Tae-Woo Kwon、Samson A. Jenekhe

  DOI：10.5012/bkcs.2012.33.8.2703

  日期：2012.8.20

  Accepted May 23, 2012New C60 fullerenes derivatives [G1]-C60 ( 1) and [G2]-C60 ( 2) comprising of phenylenevinylene bridges andphenylquinoline peripheral surface groups were synthesized by 1,3-dipolar cycloaddition reaction of fullereneC60 with azomethine ylide in situ generated from [Gx]-CHO dendrons (x = 1 and 2) and sarcosine.Key Words : C60 fullerenes, Oligoquinolie-functionalized fullerene, Phenylquinoline

  E-mail: [e-mail] 2012年4月18日接收，2012年5月23日接受由富勒烯 C60 与由 [Gx]-CHO 树突 (x = 1 和 2) 和肌氨酸生成的甲亚胺叶立德原位发生 1,3-偶极环加成反应合成。关键词：C60 富勒烯, 低聚喹啉功能化富勒烯, 苯喹啉, 共轭亚芳基 vi -nylene dendrosIntroduction 对低成本和高效地将阳光转化为电能的兴趣导致了有机材料的开发，例如富勒烯和其他共轭聚合物。自从发现 C60 富勒烯
• SITE-SPECIFIC CHEMICAL MODIFICATION OF PROTEINS AT THEIR N-TERMINI, ENABLING THE FORMATION OF HOMOGENEOUS ADDUCTS
  申请人：KRANTZ Alexander

  公开号：US20100099649A1

  公开（公告）日：2010-04-22

  Site-specific modifications of proteins at their N-termini are provided. In particular, a chemical modification of proteins at their N-termini via a transamination reaction to form homogeneous adducts such as, the corresponding oxime derivatives is provided. Methods of making and using the adducts in radio-labelling, molecular imaging applications, and treatment of disorders such as cancer, Crohn's disease, arthritis, atherothrombosis and plaque rupture are also provided.
• FUNCTIONALIZED POROUS ORGANIC POLYMERS AS URANIUM NANO-TRAPS FOR EFFICIENT URANIUM EXTRACTION
  申请人：University of South Florida

  公开号：US20210162371A1

  公开（公告）日：2021-06-03

  Compositions are provided for efficient uranium extraction, for example from wastewater, seawater, or other water sources. The compositions can include a functionalized porous organic polymer functionalized with one or more uranium binding moieties, e.g. having a plurality of amidoxime or amidrazone groups covalently attached thereto. The compositions can include covalent organic frameworks, porous aromatic frameworks, and various porous organic polymers, especially those having a hierarchical pore size distribution over a range of pore sizes. The compositions can have functional groups such as amidoxime or an amidrazone covalently attached thereto. The hierarchical pore size distribution can be determined based upon at least 60% of the pore sizes in the range of pore sizes having a pore volume of at least 0.01 cm 3 g −1 in the pore size distribution at 77 K. Methods of making the compositions and methods of using the compositions are also provided.
• US7416703B2
  申请人：——

  公开号：US7416703B2

  公开（公告）日：2008-08-26
• US7498084B2
  申请人：——

  公开号：US7498084B2

  公开（公告）日：2009-03-03