(2-methoxy-1-methylbutyl)-benzene | 92904-03-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-methoxy-1-methylbutyl)-benzene
• 英文别名: 3-methoxypentan-2-ylbenzene
• CAS: 92904-03-5
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: JZESDORJAAXTTQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  碘甲烷 在 NaH 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以58%的产率得到(2-methoxy-1-methylbutyl)-benzene
  参考文献：
  名称：

  US8071530

  摘要：

  公开号：

文献信息

• Hydrogenolysis of 1-Alkoxybenzocyclobutenes with Site-selective Cleavage of the Sterically Hindered C(sp²)–C(sp³) Bond
  作者：Shota Sawano、Naoki Ishida、Masahiro Murakami

  DOI：10.1246/cl.150719

  日期：2015.11.5

  1-Alkoxybenzocyclobutenes undergo ring-opening hydrogenolysis with site-selective cleavage of the sterically hindered C(sp2)–C(sp3) bond on Pd/C.

  1-烷氧基苯并环丁烯在Pd/C条件下经历环开氢解反应，择位选择性地断裂空间位阻的C(sp2)–C(sp3)键。
• ORGANOLEPTIC COMPOUNDS AND THEIR USE IN PERFUME COMPOSITIONS
  申请人：Smith Catherine Marie

  公开号：US20120041077A1

  公开（公告）日：2012-02-16

  The present invention a method of improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of the following compound: wherein R 1 and R 2 independently represent a straight, branched or cyclic hydrocarbon moiety consisting of less than 10, preferably less than 4, most preferably 1 of 2 carbon atoms.

  本发明涉及一种通过添加以下化合物的嗅觉可接受量来改善、增强或修改香气配方的方法：其中R1和R2独立地表示由不到10个，优选不到4个，最优选1个或2个碳原子组成的直链、支链或环烃基。
• Organoleptic compounds and their use in perfume compositions
  申请人：Smith Catherine Marie

  公开号：US08399398B2

  公开（公告）日：2013-03-19

  The present invention a method of improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of the following compound: wherein R1 and R2 independently represent a straight, branched or cyclic hydrocarbon moiety consisting of less than 10, preferably less than 4, most preferably 1 of 2 carbon atoms.

  本发明提供了一种通过添加以下化合物的嗅觉可接受量来改善、增强或修改香气配方的方法：其中R1和R2分别表示由少于10个，优选少于4个，最优选1或2个碳原子组成的直链、支链或环烃基。
• Organoleptic Compounds and Their Use In Perfume Compositions
  申请人：Smith Catherine Marie

  公开号：US20080039361A1

  公开（公告）日：2008-02-14

  The present invention a method of improving, enhancing or modifying a fragrance formulation through the addition of an olfactory acceptable amount of the following compound: wherein R 1 and R 2 independently represent a straight, branched or cyclic hydrocarbon moiety consisting of less than 10, preferably less than 4, most preferably less than 2 carbon atoms.
• US8071530B2
  申请人：——

  公开号：US8071530B2

  公开（公告）日：2011-12-06