3,4-di(3-acryloyloxypropyloxy)benzoic acid | 277761-28-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,4-di(3-acryloyloxypropyloxy)benzoic acid
• 英文别名: 3,4-Bis(3-prop-2-enoyloxypropoxy)benzoic acid
• CAS: 277761-28-1
• 化学式: C₁₉H₂₂O₈
• 分子量: 378.379
• InChiKey: UHXNMDVUQYAXRW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  27
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  108
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  3,4-di(3-acryloyloxypropyloxy)benzoic acid 、 [4-[6-(6-Prop-2-enoyloxyhexoxy)naphthalene-2-carbonyl]oxy-2-propylphenyl] 6-hydroxynaphthalene-2-carboxylate 在 4-二甲氨基吡啶 、 N,N'-二异丙基碳二亚胺 作用下， 以 四氢呋喃 为溶剂， 反应 16.5h， 以25.1%的产率得到[4-[6-[3,4-Bis(3-prop-2-enoyloxypropoxy)benzoyl]oxynaphthalene-2-carbonyl]oxy-3-propylphenyl] 6-(6-prop-2-enoyloxyhexoxy)naphthalene-2-carboxylate
  参考文献：
  名称：

  TRIFUNCTIONAL (METH)ACRYLATE COMPOUND AND POLYMERIZABLE COMPOSITION CONTAINING THE COMPOUND

  摘要：

  公开号：

  EP2261201B1

文献信息

• COMPOSITION FOR PHOTO-ALIGNMENT FILM, OPTICALLY ANISOTROPIC MATERIAL AND METHOD FOR PRODUCING SAME
  申请人：DIC Corporation

  公开号：EP1947489A1

  公开（公告）日：2008-07-23

  The present invention provides a photoalignment film composition containing a compound represented by general formula (1) and a compound having a hydrophilic group and a (meth)acryloyloxy group, an optically anisotropic medium using a photoalignment film comprised of the photoalignment film composition, and a method for preparing thereof: (wherein, R1 and R2 respectively and independently represent a hydrogen atom, halogen atom, carboxyl group or alkali metal salt thereof, halogenated methyl group, halogenated methoxy group, cyano group, nitro group, -OR5, hydroxylalkyl group having 1 to 4 carbon atoms, -CONR6k7 or methoxycarbonyl group, and R3 and R4 respectively and independently represent a carboxyl group or alkali metal salt thereof, sulfo group or alkali metal salt thereof, nitro group, amino group, carbamoyl group, alkoxycarbonyl group, sulfamoyl group or hydroxyl group).

  本发明提供了一种含有通式（1）代表的化合物和具有亲水基团和（甲基）丙烯酰氧基的化合物的光配位膜组合物、一种使用由该光配位膜组合物构成的光配位膜的光学各向异性介质，以及一种制备方法： (其中，R1 和 R2 分别独立地代表氢原子、卤素原子、羧基或其碱金属盐、卤代甲基、卤代甲氧基、氰基、硝基、-OR5、具有 1 至 4 个碳原子的羟烷基、-CONR6k7或甲氧基羰基，以及 R3 和 R4 分别独立地代表羧基或其碱金属盐、磺基或其碱金属盐、硝基、氨基、氨基甲酰基、烷氧基羰基、氨基磺酰基或羟基）。
• PHOTOALIGNMENT FILM COMPOSITION, OPTICALLY ANISOTROPIC MEDIUM AND METHOD FOR PREPARING THEREOF
  申请人：Nishiyama Isa

  公开号：US20090269513A1

  公开（公告）日：2009-10-29

  The present invention provides a photoalignment film composition containing a compound represented by general formula (1) and a compound having a hydrophilic group and a (meth)acryloyloxy group, an optically anisotropic medium using a photoalignment film comprised of the photoalignment film composition, and a method for preparing thereof: (wherein, R 1 and R 2 respectively and independently represent a hydrogen atom, halogen atom, carboxyl group or alkali metal salt thereof, halogenated methyl group, halogenated methoxy group, cyano group, nitro group, —OR 5 , hydroxylalkyl group having 1 to 4 carbon atoms, —CONR 6 R 7 or methoxycarbonyl group, and R 3 and R 4 respectively and independently represent a carboxyl group or alkali metal salt thereof, sulfo group or alkali metal salt thereof, nitro group, amino group, carbamoyl group, alkoxycarbonyl group, sulfamoyl group or hydroxyl group).
• TRIFUNCTIONAL (METH)ACRYLATE COMPOUND AND POLYMERIZABLE COMPOSITION CONTAINING SAME
  申请人：Shinano Hirokatsu

  公开号：US20110037025A1

  公开（公告）日：2011-02-17

  A trifunctional (meth)acrylate compound represented by the following general formula (I); and a polymerizable composition containing the compound. The compound preferably is a compound in which ring A1, ring A 2 , and ring A 3 in general formula (I) each is a benzene ring or naphthalene ring and at least one of the ring A 1 , ring A 2 , and ring A 3 is a naphthalene ring, or is a compound in which X 1 , X 2 , and X 3 each is —COO— or —OCO—. More preferred is a compound in which ring A 3 is a naphthalene ring. Even more preferred is the compound which by itself can retain a liquid-crystal phase at 30° C. and lower temperatures. (In the formula, M 1 , M 2 , and M 3 each represents methyl, etc.; rings A 1 , A 2 , and A 3 each represents a benzene ring, naphthalene ring, etc.; Z 1 , Z 2 , and Z 3 each represents C 1-6 alkyl, etc.; X 1 , X 2 , and X 3 each represents —COO—, —OCO—, etc.; Y 1 and Y 2 each represents -L 1 -, and Y 3 represents -L 2 -, etc. (L 1 and L 2 each represents C 1-8 alkylene); a, b, and c indicate the number of substituents of the ring A 1 , ring A 2 , and ring A 3 , respectively, and when the number of six-membered rings contained in each substituted monocycle or fused ring is expressed by u, then the a, b, and c each independently is an integer of 2u+2 or smaller, provided that at least one of the a, b, and c is an integer of 1 or larger; p's each independently is an integer of 1-8; q and r each independently is an integer of 1-3; and s and t each independently is 0 or 1, provided that s+t≧1.)
• LIQUID CRYSTAL COMPOSITION COMPRISING POLYMERIZABLE COMPOUND, AND LIQUID CRYSTAL DISPLAY ELEMENT USING SAID LIQUID CRYSTAL COMPOSITION
  申请人：Matsumoto Ken

  公开号：US20120200794A1

  公开（公告）日：2012-08-09

  Disclosed is a liquid crystal composition formed by including a polymerizable compound represented by general formula (I) in a nematic liquid crystal composition with negative dielectric anisotropy (Δε). In the formula, ring C 1 represents a benzene-1,2,4-triyl group, or the like; rings C 2 to C 4 represent a 1,4-phenylene group, a naphthalene-2,6-diyl group, or the like; M 1 to M 3 represent a hydrogen atom or a methyl group; Z 1 and Z 2 are a direct coupling, -L 1 -, -L 1 O—, -L 1 O—CO—, or the like; Z 6 is a direct coupling, -L 2 -, -OL 2 -, —O-COL 2 -, or the like; at least one of Z 1 , Z 2 , and Z 6 is not a direct coupling; L 1 and L 2 represent a C 1-10 alkylene group; Z 3 to Z 5 represent a direct coupling, an ester bond, or the like; and p, q, and r are 0 or 1, wherein 1≦p+q+r≦3.
• US7955665B2
  申请人：——

  公开号：US7955665B2

  公开（公告）日：2011-06-07