1,2,3,4,5,6-phenylhexakis(methanethiol) | 62469-17-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2,3,4,5,6-phenylhexakis(methanethiol)
• 英文别名: hexakis-mercaptomethyl-benzene；Hexakis-mercaptomethyl-benzol；(Benzene-1,2,3,4,5,6-hexayl)hexamethanethiol；[2,3,4,5,6-pentakis(sulfanylmethyl)phenyl]methanethiol
• CAS: 62469-17-4
• 化学式: C₁₂H₁₈S₆
• 分子量: 354.671
• InChiKey: LUHCJJJSCMNENH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  6
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,2,3,4,5,6-phenylhexakis(methanethiol) 、 乙酸酐 以 吡啶 为溶剂， 生成 hexakis(acetylthiomethyl)benzene
  参考文献：
  名称：

  Hexakis(mercaptomethyl)benzene: a Structure Possessing Well Ordered Homodromic [SH...S]₆Interactions

  摘要：

  In the molecular crystal of the title compound, 1,2,3,4,5,6-phenylhexakis(methanethiol), C12H18S6, an intermolecular [SH](6) grouping around a paint of (3) over bar symmetry is found between molecules which are stacked infinitely along the c-axial direction.

  DOI：

  10.1107/s0108270196010499
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium hydroxide 、 水 作用下， 生成 1,2,3,4,5,6-phenylhexakis(methanethiol)
  参考文献：
  名称：

  Backer, Recueil des Travaux Chimiques des Pays-Bas, 1935, vol. 54, p. 905,914

  摘要：

  DOI：

文献信息

• SYNTHESIS OF CYCLOPHANES FROM A SELF-ASSEMBLY REACTION
  申请人：University of Oregon

  公开号：US20160137598A1

  公开（公告）日：2016-05-19

  Disclosed herein is a novel method for preparing cyclophanes, comprising forming a disulfide cyclophane by contacting a linker moiety which includes two or more thiol groups, with a metal salt and an oxidant. The disulfide cyclophane is then desulfurized to form a thiacyclophane comprising thioether bridges. This thiacyclophane optionally may be further desulfurized to form an unsaturated hydrocarbon cyclophane, which can then be reduced to form a saturated hydrocarbon cyclophane. The various cyclophanes can be synthesized in a ring form, such as a dimer, trimer or tetramer etc., or they can be synthesized in a tetrahedral or larger structure. Also disclosed are novel cyclophanes formed by the disclosed method.

  本文揭示了一种制备环戊烷的新方法，包括通过将含有两个或更多硫醚基团的连接剂与金属盐和氧化剂接触来形成二硫化环戊烷。然后对二硫化环戊烷进行脱硫作用，形成含有硫醚桥的硫代环戊烷。这种硫代环戊烷可以选择性地进一步脱硫，形成不饱和碳氢化合物环戊烷，然后可以还原为饱和碳氢化合物环戊烷。这些不同的环戊烷可以以环形形式合成，如二聚体、三聚体或四聚体等，或者它们可以以四面体或更大的结构合成。此外，还披露了通过上述方法形成的新型环戊烷。
• Synthesis of cyclophanes for a self-assembly reaction
  申请人：University of Oregon

  公开号：US10344005B2

  公开（公告）日：2019-07-09

  Disclosed herein is a novel method for preparing cyclophanes, comprising forming a disulfide cyclophane by contacting a linker moiety which includes two or more thiol groups, with a metal salt and an oxidant. The disulfide cyclophane is then desulfurized to form a thiacyclophane comprising thioether bridges. This thiacyclophane optionally may be further desulfurized to form an unsaturated hydrocarbon cyclophane, which can then be reduced to form a saturated hydrocarbon cyclophane. The various cyclophanes can be synthesized in a ring form, such as a dimer, trimer or tetramer etc., or they can be synthesized in a tetrahedral or larger structure. Also disclosed are novel cyclophanes formed by the disclosed method.

  本文公开了一种制备环烷的新方法，该方法包括将包含两个或两个以上硫醇基团的连接分子与金属盐和氧化剂接触，形成二硫化环烷。然后将二硫化环烷脱硫，形成包含硫醚桥的硫代环烷。这种硫代环烷还可以进一步脱硫，形成不饱和烃环烷，然后再还原形成饱和烃环烷。各种环烷可合成为环状，如二聚体、三聚体或四聚体等，也可合成为四面体或更大的结构。同时公开的还有通过公开方法形成的新型环烷。
• Voegtle,F.; Weber,E., Angewandte Chemie, 1974, vol. 86, p. 896 - 898
  作者：Voegtle,F.、Weber,E.

  DOI：——

  日期：——
• Ester von 3-tert.Butyl- bzw. 3-tert.-Butyl-5-alkyl-4-hydroxyphenyl-(alkan-)-carbonsäuren mit Oxethylaten von Polythiolen, Verfahren zu ihrer Herstellung und ihre Verwendung als Stabilisatoren
  申请人：HÜLS AKTIENGESELLSCHAFT

  公开号：EP0268039B1

  公开（公告）日：1992-09-02
• LIQUID CRYSTALLINE COMPOSITION, POLYMER LIQUID CRYSTAL COMPOUND, LIGHT ABSORPTION ANISOTROPIC FILM, LAMINATE, AND IMAGE DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20190322937A1

  公开（公告）日：2019-10-24

  An object of the invention is to provide a polymer liquid crystal compound with which a light absorption anisotropic film having a high alignment degree can be formed, a liquid crystalline composition, a light absorption anisotropic film which is formed of the liquid crystalline composition, a laminate, and an image display device. A liquid crystalline composition according to an embodiment of the invention includes a polymer liquid crystal compound which contains a repeating unit represented by Formula (1) and a dichroic substance. In Formula (1), a difference between a log P value of P1, L1, and SP1 and a log P value of M1 is 4 or greater. In Formula (1), P1 represents a main chain of the repeating unit, L1 represents a single bond or a divalent linking group, SP1 represents a spacer group, M1 represents a mesogenic group, and T1 represents a terminal group.