1-(tert-butyl)-4-((4-ethylphenoxy)methyl)benzene | 1352931-31-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(tert-butyl)-4-((4-ethylphenoxy)methyl)benzene
• 英文别名: 1-Tert-butyl-4-[(4-ethylphenoxy)methyl]benzene
• CAS: 1352931-31-7
• 化学式: C₁₉H₂₄O
• 分子量: 268.399
• InChiKey: FQGWVHXNXXWYEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(tert-butyl)-4-((4-ethylphenoxy)methyl)benzene 在 叔丁基过氧化氢 作用下， 以 水 为溶剂， 反应 12.0h， 以19.5%的产率得到4-(4-tert-butylbenzyloxy)acetophenone
  参考文献：
  名称：

  A Multifunctional Organic–Inorganic Hybrid Structure Based on Mn^III–Porphyrin and Polyoxometalate as a Highly Effective Dye Scavenger and Heterogenous Catalyst

  摘要：

  A two-step synthesis strategy has led to a unique layered polyoxometalate-Mn-III-metalloporphyrin-based hybrid material. The hybrid solid demonstrates remarkable capability for scavenging of dyes and for heterogeneous selective oxidation of alkylbenzenes with excellent product yields and 100% selectivity.

  DOI：

  10.1021/ja209196t

文献信息

• A Multifunctional Organic–Inorganic Hybrid Structure Based on Mn^III–Porphyrin and Polyoxometalate as a Highly Effective Dye Scavenger and Heterogenous Catalyst
  作者：Chao Zou、Zhijuan Zhang、Xuan Xu、Qihan Gong、Jing Li、Chuan-De Wu

  DOI：10.1021/ja209196t

  日期：2012.1.11

  A two-step synthesis strategy has led to a unique layered polyoxometalate-Mn-III-metalloporphyrin-based hybrid material. The hybrid solid demonstrates remarkable capability for scavenging of dyes and for heterogeneous selective oxidation of alkylbenzenes with excellent product yields and 100% selectivity.