bis-(1-phenyl-propyl)-sulfide | 856061-93-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-(1-phenyl-propyl)-sulfide
• 英文别名: Bis-(1-phenyl-propyl)-sulfid；1-(1-Phenylpropylsulfanyl)propylbenzene
• CAS: 856061-93-3
• 化学式: C₁₈H₂₂S
• 分子量: 270.439
• InChiKey: WLIRDHRLKWCHCJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bis-(1-phenyl-propyl)-sulfide 在 双氧水 、 溶剂黄146 作用下， 生成 bis-(1-phenyl-propyl)-sulfoxide
  参考文献：
  名称：

  Bermejo; Jimenez Herrera; Martin Panizo, Anales de la Real Sociedad Espanola de Fisica y Quimica, 1934, vol. 32, p. 1182,1184

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 potassium sulfide 、 乙醇 作用下， 生成 bis-(1-phenyl-propyl)-sulfide
  参考文献：
  名称：

  Bermejo; Jimenez Herrera; Martin Panizo, Anales de la Real Sociedad Espanola de Fisica y Quimica, 1934, vol. 32, p. 1182,1184

  摘要：

  DOI：

文献信息

• Reaction method accompanied by production of gas component
  申请人：Asahi Kasei Chemicals Corporation

  公开号：US10118110B2

  公开（公告）日：2018-11-06

  The present invention relates to a reaction method comprising a step of supplying a liquid containing at least one raw material compound and a low-boiling compound having a standard boiling point lower than a standard boiling point of the raw material compound to a flow channel, a step of heating the liquid to produce a liquid reaction product and a gas component by a reaction of the raw material compound, and a step of separating a liquid phase containing the reaction product from a gas phase containing the gas component and the low-boiling compound.

  本发明涉及一种反应方法，包括以下步骤：将含有至少一种原料化合物和一个标准沸点低于原料化合物的标准沸点的低沸点化合物的液体输送到流通道中；加热液体以通过原料化合物的反应生成液体反应产物和气体组分；将含有反应产物的液相与含有气体组分和低沸点化合物的气相分离。
• METHOD FOR PRODUCING ALPHA-OLEFIN
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20140364669A1

  公开（公告）日：2014-12-11

  Provided is a production process for α-olefin which does not comply the Shultz-Flory distribution and which is excellent in the yields of α-olefins of 1-hexene up to 1-tetradecene each having 6 to 14 carbon atoms, particularly a yield of 1-octene. The above production process is characterized by polymerizing ethylene using (A) a specific chromium compound, (B) a specific aminophosphine ligand compound and (C) a promoter.

  提供了一种α-烯烃的生产工艺，该工艺不符合舒尔茨-弗洛里分布，在1-己烯至1-十四烯的α-烯烃收率方面表现出色，每种烯烃均含有6至14个碳原子，特别是1-辛烯的产率。上述生产工艺的特点是利用（A）特定的铬化合物，（B）特定的氨基膦配体化合物和（C）促进剂聚合乙烯。
• ALPHA-OLEFIN OLIGOMER AND METHOD FOR PRODUCING SAME
  申请人：Fujimora Takenori

  公开号：US20120095273A1

  公开（公告）日：2012-04-19

  Disclosed are an α-olefin oligomer including 90 mol % or more of an α-olefin unit having 6 or more carbon atoms and having a small amount of a dimer component, in which a mass ratio of a dimer, a trimer and a tetramer is specified and which does not follow the Schulz-Flory distribution, and a process for producing the same.

  本发明涉及一种α-烯烃寡聚物，其中包括90摩尔%或更多的具有6个或更多碳原子的α-烯烃单元，并含有少量二聚体组分，其中指定了二聚体、三聚体和四聚体的质量比，并且不遵循Schulz-Flory分布，以及其生产方法。
• TRANSITION METAL COMPOUND AND METHOD FOR PRODUCING OLEFIN POLYMER
  申请人：IDEMITSU KOSAN CO.,LTD.

  公开号：US20210198300A1

  公开（公告）日：2021-07-01

  A transition metal compound from Periodic Table Group 3 to 10 or lanthanide, of formula (I): In formula (I), A 1 and A 2 are independently a crosslinker of formula (II) X is a σ or π-bonding ligand, and plural Xs may differ; Y is a Lewis base, and plural Ys may differ and/or crosslink with Y or X; q is an integer from 1 to 5, representing [(valence of M)−2]; r is an integer from 0 to 3; M is a metal from Group 3 to 10 or a lanthanide; n and m are independently an integer from 0 to 4; and plural Rs may differ. In formula (II), E is C, Si, Ge, or Sn; R 1 and R 2 are independently a H, a halogen, or a C1 to C20 hydrocarbon, optionally halogenated, and may bond together to form a ring, and e is an integer from 1 to 4.

  公式（I）表示来自周期表3到10族或镧系元素的过渡金属化合物：在公式（I）中，A1和A2分别是式（II）的交联剂；X是σ或π配体，且复数个X可能不同；Y是路易斯碱基，复数个Y可能不同且/或与Y或X交联；q是整数1到5，表示[M的价-2]；r是整数0到3；M是来自3到10族或镧系的金属；n和m分别是整数0到4；复数个R可能不同。在公式（II）中，E是C、Si、Ge或Sn；R1和R2分别是H、卤素或C1到C20的烃，可选择卤化，并且可以结合形成环，e是整数1到4。
• ALPHA-OLEFIN POLYMER AND PROCESS FOR PRODUCTION THEREOF
  申请人：Fujimura Takenori

  公开号：US20100036066A1

  公开（公告）日：2010-02-11

  Provided is an α-olefin polymer having an excellent balance between a molecular weight and a melting point, which is a polymer of one or more kinds of α-olefins having 20 to 40 carbon atoms, and which meets the following requirements (1) to (4): (1) the α-olefin polymer has a molecular weight distribution (Mw/Mn) determined from its weight average molecular weight (Mw) and number average molecular weight (Mn) in terms of polystyrene measured by a GPC method of 2 or less, and has an Mw of 5,000 or less; (2) measurement of a melting point (Tm) of the α-olefin polymer with DSC shows one melting peak, a melting heat absorption (AH) calculated from an area of the melting peak is 20 J/g or more, and the melting peak has a half value width of 10° C. or less; (3) when the Mw falls within a range of 1,000 to 5,000 and an average number of carbon atoms (Cn) of the α-olefins falls within a range of 20 to 40, the Mw, the Cn, and the Tm measured with the DSC satisfy the relationship, 0.0025×Mw+(Cn×3.3812−29.5)≦Tm≦0.0025×Mw+((Cn+1)×3.3812−29.5); and (4) a stereoregularity index [M 2 ] derived from a chain of the α-olefins each having 20 to 40 carbon atoms is 20% by mol or more.

  提供的是一种α-烯烃聚合物，具有分子量和熔点之间的优异平衡，是由一种或多种具有20至40个碳原子的α-烯烃聚合而成，并满足以下要求（1）至（4）：（1）α-烯烃聚合物具有分子量分布（Mw / Mn），通过GPC法测量的聚苯乙烯的重均分子量（Mw）和数均分子量（Mn）确定为2或以下，并且具有Mw小于或等于5,000的值；（2）使用DSC测量α-烯烃聚合物的熔点（Tm）仅显示一个熔化峰，从熔化峰的面积计算出的熔化热吸收（AH）为20 J / g或更高，并且熔化峰的半值宽度为10℃或更小；（3）当Mw在1,000至5,000范围内，α-烯烃的平均碳原子数（Cn）在20至40范围内时，使用DSC测量的Mw，Cn和Tm满足关系式，0.0025×Mw +（Cn×3.3812-29.5）≦ Tm ≦0.0025×Mw +（（Cn + 1）×3.3812-29.5）;（4）从具有20至40个碳原子的α-烯烃链中派生的立体异构指数[M2]为20%摩尔或更高。