2-[1-(2,6-(diisopropylphenyl)imino)ethyl]-6-[1-(2,6-(diisopropylphenyl)imino)-4-pentenyl]pyridine | 395642-01-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[1-(2,6-(diisopropylphenyl)imino)ethyl]-6-[1-(2,6-(diisopropylphenyl)imino)-4-pentenyl]pyridine
• 英文别名: N-[2,6-di(propan-2-yl)phenyl]-1-[6-[N-[2,6-di(propan-2-yl)phenyl]-C-methylcarbonimidoyl]pyridin-2-yl]pent-4-en-1-imine
• CAS: 395642-01-0
• 化学式: C₃₆H₄₇N₃
• 分子量: 521.789
• InChiKey: BRUIONZRNJUNPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.1
• 重原子数：
  39
• 可旋转键数：
  11
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  37.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  iron(II) chloride tetrahydrate 、 2-[1-(2,6-(diisopropylphenyl)imino)ethyl]-6-[1-(2,6-(diisopropylphenyl)imino)-4-pentenyl]pyridine 以 四氢呋喃 为溶剂， 以83%的产率得到2-[1-(2,6-(diisopropylphenyl)imino)ethyl]-6-[1-(2,6-(diisopropylphenyl)imino)-4-pentenyl]pyridyliron(II) chloride
  参考文献：
  名称：

  Immobilization of Bis(imino)pyridyliron(II) Complexes on Silica

  摘要：

  The well-known catalyst precursor 2,6-bis[1-((2,6-diisopropylphenyl)imino)ethyl]pyridine (1) is functionalized by various alkenyl groups to yield the corresponding alkenyl-functionalized 2,6-bis[1-((2,6-diisopropylphenyl)imino)ethyl]pyridine ligand. Reaction of these novel functionalized bis(imino)pyridyl ligands with iron(II) chloride results in the formation of precatalysts 5-7, which possess different spacer moieties. The possibility of self-immobilization has been investigated with respect to the chain length of the alkenyl moiety. Additionally, experiments to heterogenize these functionalized iron(II) complexes on modified silica via hydrosilation are presented (8-10). The immobilization has been studied by IR, and the resulting polymers have been characterized by GPC and static light scattering.

  DOI：

  10.1021/om000939t