3,4,5-Trioctadecoxybenzohydrazide | 1269041-75-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,4,5-Trioctadecoxybenzohydrazide
• 英文别名: 3,4,5-trioctadecoxybenzohydrazide
• CAS: 1269041-75-9
• 化学式: C₆₁H₁₁₆N₂O₄
• 分子量: 941.603
• InChiKey: GGANGMBXSDVBDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  26.9
• 重原子数：
  67
• 可旋转键数：
  55
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  82.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3,4,5-Trioctadecoxybenzohydrazide 、 三醛基间苯三酚 以 乙醇 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  The first examples of supramolecular discotic C3h tris(N-salicylideneamine)s featuring inter- and intra-molecular H-bonding: synthesis and characterization

  摘要：

  Supramolecular liquid crystalline tris(N-salicylideneamine)s (TSANs) featuring both inter- and intramolecular hydrogen bonding have been synthesized and characterized for the first time. These TSANs formed by condensing 3 equiv of 3,4,5-trialkoxybenzoylhydrazine with 1,3,5-triformylphloroglucinol exist as the single C-3h-symmetric keto-enamine product solely, unlike the previously reported TSANs. Their self-assembly into supramolecular fluid hexagonal columnar phase over a wide thermal range is evidenced with the aid of optical microscopic, calorimetric, and powder X-ray diffraction techniques. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.06.124
• 作为产物：
  描述：

  methyl 3,4,5-tris(octadecyloxy)benzoate 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 5.0h， 生成 3,4,5-Trioctadecoxybenzohydrazide
  参考文献：
  名称：

  The first examples of supramolecular discotic C3h tris(N-salicylideneamine)s featuring inter- and intra-molecular H-bonding: synthesis and characterization

  摘要：

  Supramolecular liquid crystalline tris(N-salicylideneamine)s (TSANs) featuring both inter- and intramolecular hydrogen bonding have been synthesized and characterized for the first time. These TSANs formed by condensing 3 equiv of 3,4,5-trialkoxybenzoylhydrazine with 1,3,5-triformylphloroglucinol exist as the single C-3h-symmetric keto-enamine product solely, unlike the previously reported TSANs. Their self-assembly into supramolecular fluid hexagonal columnar phase over a wide thermal range is evidenced with the aid of optical microscopic, calorimetric, and powder X-ray diffraction techniques. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.06.124