1-Phenyl-2-(4-{2,2,2-trifluoro-1-[4-(2-oxo-2-phenyl-acetyl)-phenyl]-1-trifluoromethyl-ethyl}-phenyl)-ethane-1,2-dione | 55100-56-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 1-Phenyl-2-(4-{2,2,2-trifluoro-1-[4-(2-oxo-2-phenyl-acetyl)-phenyl]-1-trifluoromethyl-ethyl}-phenyl)-ethane-1,2-dione
• 英文别名: 1,1'-[(1,1,1,3,3,3-Hexafluoropropane-2,2-diyl)dibenzene-4,1-diyl]bis(2-phenylethane-1,2-dione)；1-[4-[1,1,1,3,3,3-hexafluoro-2-[4-(2-oxo-2-phenylacetyl)phenyl]propan-2-yl]phenyl]-2-phenylethane-1,2-dione
• CAS: 55100-56-6
• 化学式: C₃₁H₁₈F₆O₄
• 分子量: 568.472
• InChiKey: GPZFEFFOYGPJSU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.8
• 重原子数：
  41
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  68.3
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2,2-bis(4-phenylethynylphenyl)hexafluoropropane 在 potassium permanganate 作用下， 以 溶剂黄146 为溶剂， 以80%的产率得到1-Phenyl-2-(4-{2,2,2-trifluoro-1-[4-(2-oxo-2-phenyl-acetyl)-phenyl]-1-trifluoromethyl-ethyl}-phenyl)-ethane-1,2-dione
  参考文献：
  名称：

  Sillion, Bernard, Bulletin des Societes Chimiques Belges, 1989, vol. 98, # 9-10, p. 577 - 602

  摘要：

  DOI：

文献信息

• Novel fluorine-containing bis(tetraarylcyclopentadienones)
  作者：M. L. Keshtov、P. V. Petrovskii、A. S. Stakhanov、V. S. Kochurov、A. R. Khokhlov

  DOI：10.1134/s0012500809110068

  日期：2009.11
• [EN] METHOD FOR CROSS-LINKING OF POLYMER FILMS<br/>[FR] PROCÉDÉ DE RÉTICULATION DE FILMS DE POLYMÈRE
  申请人：STAV POLYMÉROV SAV

  公开号：WO2014209241A1

  公开（公告）日：2014-12-31

  The polymer films cross-linking method is based on the use as additive of low-molecular compound containing two 1,2-dicarbonyl groups at least, dissolved in the polymer in the amount between 1.2 and 11.7% (related to the polymer mass). The low-molecular compound is photoperoxidized by visible light and UV light in presence of oxygen till the 1,2-dicarbonyl groups are consumed by the formation of diacyl peroxide structures, decomposed subsequently by light or heat, thus creating the cross-linked polymer. The consumption of 1,2-dicarbonyl structures during the photoperoxidation and the subsequent decomposition of the diacyl peroxide groups at the generation of the cross-linked polymer is monitored according to the changes in IR spectra.