Phenyl-bis-[4-(phenyl-hydrazonomethyl)-phenyl]-amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Phenyl-bis-[4-(phenyl-hydrazonomethyl)-phenyl]-amine
• 英文别名: N-phenyl-4-[(E)-(phenylhydrazinylidene)methyl]-N-[4-[(E)-(phenylhydrazinylidene)methyl]phenyl]aniline
• 化学式: C₃₂H₂₇N₅
• 分子量: 481.6
• InChiKey: QZVTTYCUNKNRIL-WASGUHIUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  37
• 可旋转键数：
  9
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  Phenyl-bis-[4-(phenyl-hydrazonomethyl)-phenyl]-amine 、 环氧氯丙烷 在 氢氧化钾 、 sodium sulfate 作用下， 以52%的产率得到4-(4-formyldiphenylamino)benzaldehyde bis-(N-2,3-epoxypropyl-N-phenyl)hydrazine
  参考文献：
  名称：

  An Efficient Scalable Synthesis of 2,3-Epoxypropyl Phenylhydrazones

  摘要：

  以9-乙基-3-咔唑甲醛、9-乙基-3,6-咔唑二甲醛、4 -二甲基-氨基-、4-二乙基氨基-、4-苄基乙基氨基-、4-(二苯基氨基)-、4-(4,4-4'-二甲基-二苯基氨基)-、4-(4-甲酰基二苯基氨基)-和4- (4-甲酰基-4'-甲基二苯基氨基)苯甲醛与环氧氯丙烷在 KOH 和无水 Na2SO4 存在下反应。

  DOI：

  10.3390/11010064
• 作为产物：
  描述：

  N,N-二(4-甲酰苯基)苯胺 、 苯肼 以 四氢呋喃 为溶剂， 反应 0.17h， 生成 Phenyl-bis-[4-(phenyl-hydrazonomethyl)-phenyl]-amine
  参考文献：
  名称：

  An Efficient Scalable Synthesis of 2,3-Epoxypropyl Phenylhydrazones

  摘要：

  以9-乙基-3-咔唑甲醛、9-乙基-3,6-咔唑二甲醛、4 -二甲基-氨基-、4-二乙基氨基-、4-苄基乙基氨基-、4-(二苯基氨基)-、4-(4,4-4'-二甲基-二苯基氨基)-、4-(4-甲酰基二苯基氨基)-和4- (4-甲酰基-4'-甲基二苯基氨基)苯甲醛与环氧氯丙烷在 KOH 和无水 Na2SO4 存在下反应。

  DOI：

  10.3390/11010064

文献信息

• ORGANIC DYES COMPRISING A HYDRAZONE MOIETY AND THEIR USE IN DYE-SENSITIZED SOLAR CELLS
  申请人：BASF SE

  公开号：US20160126022A1

  公开（公告）日：2016-05-05

  The present invention relates to compounds of general formula I wherein R 100 and R 200 are each independently hydrogen, C 1 -C 10 -alkyl which in case of C 2 -alkyl may be interrupted by one and in case of C 3 -C 10 -alkyl by one or two non-adjacent oxygen atoms, C 5 -C 7 -cycloalkyl, aryl, aryl-C 1 -C 10 -alkyl or aryloxy-C 1 -C 10 -alkyl, D is an m-valent (m=1, 2 or 3) donor moiety which comprises at least one carbon-carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, A is an acceptor moiety which comprises at least one carbon-carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, and the donor moiety D and the acceptor moiety A are π-conjugated to one another. Furthermore, the present invention relates to the use of compounds of formula I for producing dye-sensitized solar cells and to dye-sensitized solar cells comprising compounds of formula I.
• US9831042B2
  申请人：——

  公开号：US9831042B2

  公开（公告）日：2017-11-28
• [EN] ORGANIC DYES COMPRISING A HYDRAZONE MOIETY AND THEIR USE IN DYE-SENSITIZED SOLAR CELLS<br/>[FR] COLORANTS ORGANIQUES COMPRENANT UNE PARTIE D'HYDRAZONE ET LEUR UTILISATION DANS DES PILES SOLAIRES À COLORANTS
  申请人：BASF SE

  公开号：WO2014006544A2

  公开（公告）日：2014-01-09

  The present invention relates to compounds of general formula (I) wherein R100 and R200 are each independently hydrogen, C1-C10-alkyl which in case of C2-alkyl may be interrupted by one and in case of C3-C10-alkyl by one or two non- adjacent oxygen atoms, C5-C7-cycloalkyl, aryl, aryl-C1-C10-alkyl or aryloxy-C1-C10-alkyl, D is an m-valent (m = 1, 2 or 3) donor moiety which comprises at least one carbon- carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, A is an acceptor moiety which comprises at least one carbon- carbon or carbon-heteroatom double bond and/or at least one unfused or fused carbo- or heterocyclic ring, and the donor moiety D and the acceptor moiety A are π- conjugated to one another. Furthermore, the present invention relates to the use of compounds of formula (I) for producing dye-sensitized solar cells and to dye-sensitized solar cells comprising compounds of formula (I).
• An Efficient Scalable Synthesis of 2,3-Epoxypropyl Phenylhydrazones
  作者：Vytautas Getautis、Maryte Daskeviciene、Tadas Malinauskas、Albina Stanisauskaite、Jolanta Stumbraite

  DOI：10.3390/11010064

  日期：——

  A series of mono and di-N-2,3-epoxypropyl N-phenylhydrazones have beenprepared on a large scale by reaction of the corresponding N-phenylhydrazones of9-ethyl-3-carbazolecarbaldehyde, 9-ethyl-3,6-carbazoledicarbaldehyde, 4-dimethyl-amino-, 4-diethylamino-, 4-benzylethylamino-, 4-(diphenylamino)-, 4-(4,4-4'-dimethyl-diphenylamino)-, 4-(4-formyldiphenylamino)- and 4-(4-formyl-4'-methyldiphenyl-amino)benzaldehyde with epichlorohydrin in the presence of KOH and anhydrousNa2SO4.

  以9-乙基-3-咔唑甲醛、9-乙基-3,6-咔唑二甲醛、4 -二甲基-氨基-、4-二乙基氨基-、4-苄基乙基氨基-、4-(二苯基氨基)-、4-(4,4-4'-二甲基-二苯基氨基)-、4-(4-甲酰基二苯基氨基)-和4- (4-甲酰基-4'-甲基二苯基氨基)苯甲醛与环氧氯丙烷在 KOH 和无水 Na2SO4 存在下反应。