3,4,6,7-tetrathio-9-hydroxyphenalen-1-one | 1425265-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3,4,6,7-tetrathio-9-hydroxyphenalen-1-one
• 英文别名: 8-Hydroxy-2,3,11,12-tetrathiapentacyclo[11.3.1.04,16.07,15.010,14]heptadeca-1(16),4,7(15),8,10(14),13(17)-hexaen-6-one；8-hydroxy-2,3,11,12-tetrathiapentacyclo[11.3.1.04,16.07,15.010,14]heptadeca-1(16),4,7(15),8,10(14),13(17)-hexaen-6-one
• CAS: 1425265-61-7
• 化学式: C₁₃H₄O₂S₄
• 分子量: 320.438
• InChiKey: LCJSJNLTGFXLEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  139
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  三氟甲磺酸 、 3,4,6,7-tetrathio-9-hydroxyphenalen-1-one 在 劳森试剂 作用下， 以 氯苯 为溶剂， 反应 36.0h， 以8%的产率得到1,2,4,5,7,8-hexathiophenalenylium triflate
  参考文献：
  名称：

  Hexathiophenalenylium Cations: Syntheses, Structures, and Redox Chemistry

  摘要：

  Preparations of two hexathiophenalenylium compounds as stable salts from the reaction of 3,4,6,7-tetrathio-9-hydroxyphenalenone with Lawesson's reagent have been reported. The presence of three disulfide linkages on the periphery of the core phenalenyl unit is confirmed by X-ray crystallographic characterizations. Electrochemical cell potentials are lower than those of related dithio- and tetrathio-bridged phenalenyl radicals, and the hexathiophenalenyl radical shows a strong electron paramagnetic resonance (EPR) signal in the solid state.

  DOI：

  10.1021/ol400452f
• 作为产物：
  描述：

  1,3,6,8-tetramethoxynaphthalene 在 盐酸 、 水 、 吡啶盐酸盐 、 三乙胺 、 potassium thioacetate 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 反应 95.0h， 生成 3,4,6,7-tetrathio-9-hydroxyphenalen-1-one
  参考文献：
  名称：

  Hexathiophenalenylium Cations: Syntheses, Structures, and Redox Chemistry

  摘要：

  Preparations of two hexathiophenalenylium compounds as stable salts from the reaction of 3,4,6,7-tetrathio-9-hydroxyphenalenone with Lawesson's reagent have been reported. The presence of three disulfide linkages on the periphery of the core phenalenyl unit is confirmed by X-ray crystallographic characterizations. Electrochemical cell potentials are lower than those of related dithio- and tetrathio-bridged phenalenyl radicals, and the hexathiophenalenyl radical shows a strong electron paramagnetic resonance (EPR) signal in the solid state.

  DOI：

  10.1021/ol400452f

文献信息

• Synthesis of Tetrachalcogenide-Substituted Phenalenyl Derivatives: Preparation and Solid-State Characterization of Bis(3,4,6,7-tetrathioalkyl-phenalenyl)boron Radicals
  作者：Pradip Bag、Sushanta K. Pal、Mikhail E. Itkis、Arindam Sarkar、Fook S. Tham、Bruno Donnadieu、Robert C. Haddon

  DOI：10.1021/ja405814f

  日期：2013.9.4

  We report the synthesis and properties of a series of spiro-bis(3,4,6,7-tetrachalcogenide-substituted-phenalenyl)boron salts and two of the corresponding tetrathioalkyl-substituted spiro-bis(phenalenyl)boron radicals [tetrathiomethyl (10) and tetrathioethyl (11)] in which all of the active positions of the phenalenyl (PLY) nucleus are functionalized. In the solid state, radicals 10 and 11 exist as a weak pi-dimers due to the steric congestion of the thioalkyl groups in the superimposed PLY units. As a result, the spins are localized in the isolated (nonsuperimposed) PLY rings, and the structure, magnetic susceptibility measurements, and band structure calculations confirm that these PLY units are unable to undergo strong intermolecular interaction as a result of the orientation of the thioalkyl groups.
• Hexathiophenalenylium Cations: Syntheses, Structures, and Redox Chemistry
  作者：Pradip Bag、Fook S. Tham、Bruno Donnadieu、Robert C. Haddon

  DOI：10.1021/ol400452f

  日期：2013.3.15

  Preparations of two hexathiophenalenylium compounds as stable salts from the reaction of 3,4,6,7-tetrathio-9-hydroxyphenalenone with Lawesson's reagent have been reported. The presence of three disulfide linkages on the periphery of the core phenalenyl unit is confirmed by X-ray crystallographic characterizations. Electrochemical cell potentials are lower than those of related dithio- and tetrathio-bridged phenalenyl radicals, and the hexathiophenalenyl radical shows a strong electron paramagnetic resonance (EPR) signal in the solid state.