(N-benzenesulphonylglycinato-NO)triaquacopper(II) | 135728-58-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N-benzenesulphonylglycinato-NO)triaquacopper(II)
• CAS: 135728-58-4
• 化学式: C₈H₁₃CuNO₇S
• 分子量: 330.806
• InChiKey: XEJGTAAPSCJUEI-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (N-benzenesulphonylglycinato-NO)triaquacopper(II) 在 (C₅H₄N)2 作用下， 以 甲醇 、 水 为溶剂， 生成 {Cu(2,2'-bipyridine)(N-benzenesulphonylglycinate)(H2O)}
  参考文献：
  名称：

  Copper(II) complexes with N-sulphonyl amino acids. Structure-stability relationships in binary species and ternary complexes with 2,2′-bipyridine

  摘要：

  The stability of a series of binary and ternary 2,2'-bipyridine(bipy) complexes of Cu2+ with amino acids N-substituted by an arene sulphonic group has been analysed in 0.1 mol dm-3 NaClO4 or NaNO3 at 25-degrees-C. The stability constants determined by d.c. polarography are sensitive to the nature of the amino acid and of the aromatic moiety of the protecting group. The known lowering effect of bipy on the pK for metal-promoted sulphonamide nitrogen deprotonation in the ternary complexes is found to be quantitatively independent of the above structural features. The X-ray structure of the ternary species [Cu(bipy)(Bs-GlyNO)(H2O)] [Bs-GlyNO = N-benzenesulphonylglycinate(2-)] is also presented. The crystals are monoclinic, space group P2(1)/c, with a = 8.494(5), = 19.950(4), c = 11.295(7) angstrom, beta = 110.79(4)-degrees, Z = 4, and R = 0.036. The structure consists of [Cu(bipy)(Bs-GlyNO)(H2O)] units in which the Cu atom exhibits a tetrahedrally distorted square-pyramidal N3O2 coordination.

  DOI：

  10.1039/dt9910002961
• 作为产物：
  描述：

  苯磺酰基氨基乙酸 、 copper(II) acetate monohydrate 以 水 为溶剂， 生成 (N-benzenesulphonylglycinato-NO)triaquacopper(II)
  参考文献：
  名称：

  Structural and spectroscopic properties of N-benzenesulphonylglycine complexes with copper (II)

  摘要：

  In this paper are reported structural and spectroscopic properties of (N-benzenesulphonylglycinato) triaquacopper (II) (complex I) and dipotassium bis (N-benzenesulphonylglycinato) cuprate (II) (complex II). The crystals of (I) are monoclinic, space group P2(1)/c, Z = 4, with a = 12.736(4), b = 10.292(3), c = 10.402(3) angstrom, beta = 109.41(2)-degrees while those of complex (II) are orthorhombic, space group Pbca, with a = 23.333(8), b = 10.508(4), c = 16.989(5) angstrom. In both complexes the aminoacid molecules act as bidentate via carboxylic oxygen and the amide nitrogen atom; in (I) three water molecules complete the coordination to tetragonal pyramidal, while in (II) coordination is square planar, tetrahedrally distorted involving two ligand molecules. The structure (I) was refined to a final R index of 0.0596 and (II) to R = 0.0466.

  DOI：

  10.1007/bf01156083