| 1374313-92-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• CAS: 1374313-92-4
• 化学式: C₂₇H₂₉N₂O₂P
• 分子量: 444.513
• InChiKey: ARDIQJOACHOMDO-UHFFFAOYSA-N

物化性质

• 沸点：
  623.8±65.0 °C(Predicted)

反应信息

• 作为产物：
  描述：

  3-氨基吡啶 、 在 base 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Influence of Phosphoramidites in Copper-Catalyzed Conjugate Borylation Reaction

  摘要：

  Copper(I) has become the preferred metal to catalyze the beta-boration of alpha,beta-unsaturated carbonyl compounds, and now we demonstrate that easily accessible monodentate chiral ligands, such as phosphoramidites and phosphites, can be convenient alternative ligands to induce asymmetry in the enantioselective version of this reaction, particularly in the beta-boration of alpha,beta-unsaturated imines.

  DOI：

  10.1021/om300194k
• 作为试剂：
  描述：

  (肉)桂腈 、 联硼酸频那醇酯 在 甲醇 、 C₂₇H₂₉N₂O₂P 、 sodium t-butanolate 、 [Cu(MeCN)₄](OTf) 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以54%的产率得到
  参考文献：
  名称：

  Influence of Phosphoramidites in Copper-Catalyzed Conjugate Borylation Reaction

  摘要：

  Copper(I) has become the preferred metal to catalyze the beta-boration of alpha,beta-unsaturated carbonyl compounds, and now we demonstrate that easily accessible monodentate chiral ligands, such as phosphoramidites and phosphites, can be convenient alternative ligands to induce asymmetry in the enantioselective version of this reaction, particularly in the beta-boration of alpha,beta-unsaturated imines.

  DOI：

  10.1021/om300194k