[MoO₂(salicylideneaminophenolato)]₂ | 67598-36-1

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: [MoO₂(salicylideneaminophenolato)]₂
• 英文别名: [MoO₂(SAP)]₂；MoO2(sap)；[MoO2(N-salicylidene-2-aminophenolato(2-))]
• CAS: 67598-36-1
• 化学式: C₁₃H₉MoNO₄
• 分子量: 339.159
• InChiKey: GCSIBPRHJYBMGT-LQFHBUQSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [MoO₂(salicylideneaminophenolato)]₂ 在 N,N-二甲基甲酰胺 作用下， 以 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 以70%的产率得到MoO(2-salicylideneaminophenolate)(DMF)
  参考文献：
  名称：

  Molybdenum(IV)-oxo complexes with oxygen, nitrogen and sulfur ligands. Syntheses and electrochemical studies

  摘要：

  DOI：

  10.1021/ic00134a066
• 作为产物：
  描述：

  MoO2(N-salicylidene-2-aminophenolate)(CH3OH) 生成 [MoO₂(salicylideneaminophenolato)]₂
  参考文献：
  名称：

  OH-substituted tridentate ONO Schiff base ligands and related molybdenum(VI) complexes for solvent-free (ep)oxidation catalysis with TBHP as oxidant

  摘要：

  Molybdenum complexes with ONO tridentate Schiff base ligands based on salicylideneaminophenolato (SAP) backbone with OH substitution on the salicyl arene ring have been synthesized and characterized. The molecular structures of the full series of OH substituted molybdenum complexes were determined by X-ray crystallography as monomers stabilized by one solvent molecule, [MoO2L(D)]. All dimeric complexes [MoO2L](2) were tested for the epoxidation of cyclooctene and cyclohexene under organic solvent-free conditions using aqueous TBHP as oxidant. The position of the OH on the SAP-modified ligand influenced the catalytic activity of the respective complexes. DFT calculations for the catalytic cycle yield energy spans in agreement with the experimentally observed activity trend. (C) 2016 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2016.02.021