RuCl2(3-phenylpropyldiphenylphosphine)(MeCN)3 | 209625-72-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: RuCl2(3-phenylpropyldiphenylphosphine)(MeCN)3
• 英文别名: acetonitrile;dichlororuthenium;diphenyl(3-phenylpropyl)phosphane
• CAS: 209625-72-9
• 化学式: C₂₇H₃₀Cl₂N₃PRu
• 分子量: 599.505
• InChiKey: LKBKXOOGUJOHIG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η(6)-p-cymene)RuCl2(3-phenylpropyldiphenylphosphine) 、 乙腈 以 乙腈 为溶剂， 生成 RuCl2(3-phenylpropyldiphenylphosphine)(MeCN)3
  参考文献：
  名称：

  Synthesis and structure of a chelating arene–ruthenium complex [RuCl2(PPh2(CH2)3-η6-C6H5)]

  摘要：

  The synthesis of an arene-phosphine ligand, Ph2P(CH2)(3)Ph, has provided a route into a new chelating arene-phosphine-ruthenium complex, [RuCl2(PPh2(CH2)(3)-eta(6)-C6H5)] which has been structurally characterized. This complex can be made by thermolysis of [(eta(6)-MeC6H4CHMe2)RuCl2(PPh2(CH2)(3)Ph)] or electrochemically utilizing the formation of the labile seventeen-electron ruthenium(III) species [(eta(6)-MeC6H4CHMe2)RuCl2(PPh2(CH2)(3)Ph)](+) which can be converted in good yield into [RuCl2(PPh2(CH2)(3)-eta(6)-C6H5)]. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(97)00750-x