N,N-二-(2-甲氧基乙基)羟胺 | 5815-11-2

• 物质功能分类: 化学试剂 - 有机试剂 - 羟胺
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: N,N-二-(2-甲氧基乙基)羟胺
• 英文名称: N,N-Bis-2-Methoxyaethyl-hydroxylamin
• 英文别名: Bis(β-methoxyethyl)hydroxylamin；bis(2-methoxyethyl)hydroxylamine；N,N-bis(2-methoxy-ethyl)-hydroxylamine；bis-N,N-(2-methoxyethyl)-hydroxylamine；bis-N,N-methoxyethylhydroxylamine；Ethanamine, N-hydroxy-2-methoxy-N-(2-methoxyethyl)-；N,N-bis(2-methoxyethyl)hydroxylamine
• CAS: 5815-11-2
• 化学式: C₆H₁₅NO₃
• mdl: MFCD07779283
• 分子量: 149.19
• InChiKey: BJOXIRAGBLTXIZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  41.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  双(2-甲氧基乙基)胺 在 双氧水 作用下， 生成 N,N-二-(2-甲氧基乙基)羟胺
  参考文献：
  名称：

  Sayigh,A.A.R.; Ulrich,H., Journal of the Chemical Society, 1963, p. 3144 - 3146

  摘要：

  DOI：

文献信息

• Photographic products and processes
  申请人：POLAROID CORPORATION

  公开号：EP0127897A2

  公开（公告）日：1984-12-12

  This invention relates to photographic processes and products for forming an image in dye from a colorless precursor of a preformed image dye which is substituted with a moiety comprising a 1,3-sulfur-nitrogen group that undergoes cleavage in the presence of silver ion and/or soluble silver complex, which moiety maintains said precursor in its colorless form at least until the 1,3-suifur-nitrogen group undergoes cleavage imagewise to correspond to the imagewise distribution of silver ion and/or soluble silver complex made available as a function of development.

  本发明涉及一种照相工艺和产品，该工艺和产品用于在染料中形成图像，该染料来自一种预成图像染料的无色前体，该前体被一个包含 1,3-硫-氮基团的分子取代，该分子在银离子和/或可溶性银络合物存在下发生裂解，该分子至少在 1,3-硫-氮基团发生图像裂解之前保持所述前体的无色形式，以便与作为显影函数的银离子和/或可溶性银络合物的图像分布相对应。
• Photographic element
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0464609A2

  公开（公告）日：1992-01-08

  A photographic element comprising a support having thereon at least one layer comprising a polymer obtained by copolymerizing a repeating unit represented by the following general formula (I) and a copolymerizable cellulose derivative represented by the following general formula (II): wherein A represents a repeating unit derived from an ethylenically unsaturated monomer having -COOH group, -SO3H group or -PO(OH)2 group in the molecular structure; and B represents a repeating unit derived from a copolymerizable ethylenically unsaturated monomer; wherein (R1)s each independently represents (i) a hydrogen atom, (ii) a monovalent organic bonding group such as an ester group or an ether group or (iii) a monovalent organic bonding group represented by the following general formula (III), with the proviso that (R1)s do not all hydrogen atom at the same time; and n represents a number of 20 to 800; wherein R2 represents hydrogen atom or an alkyl group having 1 to 6 carbon atoms; and L represents a bivalent organic bonding group, and wherein the percentage by weight of the component represented by general formula (I) in the copolymer is from 5 to 95; the percentage by weight of the component represented by general formula (III) based on the weight of the component represented by general formula (II) is from 0.00001 to 10; x and y represent each the percentage by weight of each monomer component in the copolymer and x is in the range of 1 to 95 and y is in the range of 5 to 99.

  一种照相元件，包括一个支撑体，支撑体上至少有一层，该层包括由以下通式(I)表示的重复单元和以下通式(II)表示的可共聚纤维素衍生物共聚而成的聚合物： 其中 A 代表由乙烯基不饱和单体衍生的重复单元，其分子结构中具有-COOH 基团、-SO3H 基团或-PO(OH)2 基团；B 代表由可共聚的乙烯基不饱和单体衍生的重复单元； 其中(R1)s 各自独立地代表(i)氢原子，(ii)一价有机键合基团，如酯基或醚基，或(iii)由下式通式(III)代表的一价有机键合基团，但(R1)s 并非同时都是氢原子；n 代表 20 至 800 之间的数字； 其中 R2 代表氢原子或具有 1 至 6 个碳原子的烷基；和 L 代表二价有机键基，其中通式(I)所代表的组分在共聚物中的重量百分比为 5 至 95；通式(III)所代表的组分相对于通式(II)所代表的组分的重量百分比为 0.00001 至 10；x 和 y 分别代表各单体组分在共聚物中的重量百分比，x 在 1 至 95 的范围内，y 在 5 至 99 的范围内。
• Reversible redox-controlled imaging methods
  申请人：POLAROID CORPORATION

  公开号：EP0516163A1

  公开（公告）日：1992-12-02

  A novel class of N-substituted triarylmethane sulfonamides is provided which undergo reversible oxidation into colored form and reversible reduction of the oxidized form into colorless form. Preferred embodiments comprise xanthene sulfonamides having N-aryl substituents, e.g., hydroquinone substituents. These compounds possess redox potentials ranging between about +200 to -500 millivolts and thus are useful as dyes for producing photographic, photothermographic, thermal, and pressure-induced images, as well as being useful as redox indicators in a wide variety of biological and chemical reactions.

  本发明提供了一类新型的 N-取代三芳基甲烷磺酰胺，该类磺酰胺可逆氧化成有色形式，氧化形式可逆还原成无色形式。优选的实施方案包括具有 N-芳基取代基（如对苯二酚取代基）的呫吨磺酰胺。这些化合物具有的氧化还原电位范围在 +200 至 -500 毫伏之间，因此可用作染料，用于产生照相、光热成像、热成像和压力诱导成像，还可用作各种生物和化学反应中的氧化还原指示剂。
• Verfahren zur Oxidation organischer Substrate und Katalysatorzusammensetzung zur Durchführung des Verfahrens
  申请人：Evonik Degussa GmbH

  公开号：EP1514873B1

  公开（公告）日：2008-03-19
• Photographic products and processes as well as color providing compounds
  申请人：POLAROID CORPORATION

  公开号：EP0173404B1

  公开（公告）日：1988-11-02