2,4-dimethoxy-6-methyl-isophthalic acid-3-methyl ester | 108016-89-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-dimethoxy-6-methyl-isophthalic acid-3-methyl ester
• 英文别名: 2,4-Dimethoxy-6-methyl-isophthalsaeure-3-methylester；2,4-Dimethoxy-3-methoxycarbonyl-6-methylbenzoic acid；2,4-dimethoxy-3-methoxycarbonyl-6-methylbenzoic acid
• CAS: 108016-89-3
• 化学式: C₁₂H₁₄O₆
• 分子量: 254.24
• InChiKey: FTGAZJZORIYVIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  82.1
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,4-dimethoxy-6-methyl-isophthalic acid-3-methyl ester 生成 2,6-dimethoxy-4-methyl-benzoic acid methyl ester
  参考文献：
  名称：

  Identifying and mapping cDNA fragments related to rice photoperiod sensitive genic male sterility

  摘要：

  The differentially expressed cDNA fragments have been obtained by differential screening with cDNA-RAPD technique in photoperiod sensitive genic male sterile (PGMS) rice. Some of them have been reassessed with Northern blot hybridization, from which a PGMS-related positive fragment, RPG43, has been identified. Further analysis on RPG43 with Southern blot and RAPD indicates that the fragment is a single-copy sequence and its mRNA has been processed after transcription. Sequence analysis reveals that RPG43 is 744 bp in length and contains a 60 bp region (from 126th to 185th bp) showing 72% homology to a human DNA sequence, pac pDJ-356d6, on chromosome 11. So it is a new sequence found in plant and its GenBank access number is AF126027. In addition, RPG43 has been mapped to a position 3.8 cM away from RFLP marker R1553 on chromosome 5 of rice.

  DOI：

  10.1007/bf02887101
• 作为产物：
  描述：

  squamatic Acid 在 甲酸 、 丙酮 作用下， 生成 2,4-dimethoxy-6-methyl-isophthalic acid-3-methyl ester
  参考文献：
  名称：

  Asahina; Tanase, Chemische Berichte, 1937, vol. 70, p. 62

  摘要：

  DOI：

文献信息

• Huang et al., Huaxue Xuebao/Acta Chimica Sinica, 1958, vol. 24, p. 311,317
  作者：Huang et al.

  DOI：——

  日期：——
• Aoki, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1943, vol. 63, p. 45,49
  作者：Aoki

  DOI：——

  日期：——
• On the problem of constructing intermediate trajectories in the theory of elastic-Earth rotation around a center of mass
  作者：L. I. Konkina、Yu. G. Markov、A. M. Mikisha、L. V. Rykhlova

  DOI：10.1134/1.1342447

  日期：2000.12
• Identifying and mapping cDNA fragments related to rice photoperiod sensitive genic male sterility
  作者：Shuye Jiang、Qifeng Chen、Xuanjun Fang

  DOI：10.1007/bf02887101

  日期：2000.3

  The differentially expressed cDNA fragments have been obtained by differential screening with cDNA-RAPD technique in photoperiod sensitive genic male sterile (PGMS) rice. Some of them have been reassessed with Northern blot hybridization, from which a PGMS-related positive fragment, RPG43, has been identified. Further analysis on RPG43 with Southern blot and RAPD indicates that the fragment is a single-copy sequence and its mRNA has been processed after transcription. Sequence analysis reveals that RPG43 is 744 bp in length and contains a 60 bp region (from 126th to 185th bp) showing 72% homology to a human DNA sequence, pac pDJ-356d6, on chromosome 11. So it is a new sequence found in plant and its GenBank access number is AF126027. In addition, RPG43 has been mapped to a position 3.8 cM away from RFLP marker R1553 on chromosome 5 of rice.
• Asahina; Tanase, Chemische Berichte, 1937, vol. 70, p. 62
  作者：Asahina、Tanase

  DOI：——

  日期：——