dichloro-platinum phthalocyanine | 58249-04-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: dichloro-platinum phthalocyanine
• 英文别名: Dichloroplatinum(2+);2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene
• CAS: 58249-04-0
• 化学式: C₃₂H₁₆Cl₂N₈Pt
• 分子量: 778.519
• InChiKey: YCHFSBXBYAQCAU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  43
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  喹啉 、 1,2-二氰基苯 、 platinum(II) chloride 以 neat (no solvent) 为溶剂， 生成 dichloro-platinum phthalocyanine
  参考文献：
  名称：

  Phase behaviour of halogenated metal phthalocyanines

  摘要：

  The phase behaviour of chloro-aluminium phthalocyanine, chloro-indium phthalocyanine, bromoindium phthalocyanine, dichloro-tin phthalocyanine, and dichloro-platinum phthalocyanine is studied using differential scanning calorimetry, X-ray diffraction, and X-ray fluorescence. The shape of the thermograms obtained in the temperature range 150 to 350-degrees-C shows that the alpha-beta transition is characterized by two peaks of different magnitudes. The exothermic/endothermic behaviour varies for these materials suggesting that the phase transition may involve different mechanisms for different chlorinated compounds.

  DOI：

  10.1002/pssa.2211440110