[Pt(COMe)2Cl(H)(2,2'-bipyrazine)] | 1043688-23-8

• 英文名称: [Pt(COMe)2Cl(H)(2,2'-bipyrazine)]
• CAS: 1043688-23-8
• 化学式: C₁₂H₁₃ClN₄O₂Pt
• 分子量: 475.794
• InChiKey: SUZGIGOWGSBWEB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(COMe)2Cl(H)(2,2'-bipyrazine)] 在 sodium hydroxide 作用下， 以 二氯甲烷 、 水 为溶剂， 以75%的产率得到[Pt(COMe)2(2,2'-bipyrazine)]
  参考文献：
  名称：

  From platina-β-diketones to diacetylplatinum(II) complexes – Synthesis, characterization and structural features

  摘要：

  The reaction of the electronically unsaturated platina-beta-diketone [Pt(2){(COMe)(2)H}(2)(mu-Cl)(2)] (1a) with N boolean AND N donors led to the formation of diacetyl(hydrido) platinum(IV) complexes [Pt(COMe)(2)Cl(H)(N boolean AND N)] (2). By the reaction of these complexes with NaOH in a two-phase system (H(2)O/CH(2)Cl(2)) diacetylplatinum(II) complexes [Pt(COMe)(2)(N boolean AND N)] (N boolean AND N = bpy, 4a; 4,4'-Me(2)-bpy, 4b; 4,4'-t-Bu(2)-bpy, 4c; 4,4'-Ph(2)-bpy, 4d; 4,4'-t-Bu(2)-6-n-Bu-bpy, 4e; bpym, 4f; bpyr, 4g; phen, 4h; 4-Me-phen, 4i; 5-Me-phen, 4j) were obtained. All complexes were characterized by microanalysis, IR and (1)H and (13)C NMR spectroscopy. Additionally, complexes 4a, 4c, 4d and 4e were characterized by single-crystal X-ray diffraction analysis. The observed variety of packing patterns resulting from pi-pi stacking and hydrogen bonding is discussed. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.04.016
• 作为产物：
  描述：

  2,2'-联吡嗪 、 [Pt2(μ-Cl)2((COMe)2H)2] 以 二氯甲烷 为溶剂， 生成 [Pt(COMe)2Cl(H)(2,2'-bipyrazine)]
  参考文献：
  名称：

  From platina-β-diketones to diacetylplatinum(II) complexes – Synthesis, characterization and structural features

  摘要：

  The reaction of the electronically unsaturated platina-beta-diketone [Pt(2){(COMe)(2)H}(2)(mu-Cl)(2)] (1a) with N boolean AND N donors led to the formation of diacetyl(hydrido) platinum(IV) complexes [Pt(COMe)(2)Cl(H)(N boolean AND N)] (2). By the reaction of these complexes with NaOH in a two-phase system (H(2)O/CH(2)Cl(2)) diacetylplatinum(II) complexes [Pt(COMe)(2)(N boolean AND N)] (N boolean AND N = bpy, 4a; 4,4'-Me(2)-bpy, 4b; 4,4'-t-Bu(2)-bpy, 4c; 4,4'-Ph(2)-bpy, 4d; 4,4'-t-Bu(2)-6-n-Bu-bpy, 4e; bpym, 4f; bpyr, 4g; phen, 4h; 4-Me-phen, 4i; 5-Me-phen, 4j) were obtained. All complexes were characterized by microanalysis, IR and (1)H and (13)C NMR spectroscopy. Additionally, complexes 4a, 4c, 4d and 4e were characterized by single-crystal X-ray diffraction analysis. The observed variety of packing patterns resulting from pi-pi stacking and hydrogen bonding is discussed. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.04.016