Bis(hex-5-enyl) 5-[5-[5-[3,5-bis(hex-5-enoxycarbonyl)phenyl]thiophen-2-yl]thiophen-2-yl]benzene-1,3-dicarboxylate | 1082540-33-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Bis(hex-5-enyl) 5-[5-[5-[3,5-bis(hex-5-enoxycarbonyl)phenyl]thiophen-2-yl]thiophen-2-yl]benzene-1,3-dicarboxylate
• CAS: 1082540-33-7
• 化学式: C₄₈H₅₄O₈S₂
• 分子量: 823.084
• InChiKey: HMLMOJWGJRJRLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  58
• 可旋转键数：
  31
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  162
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  dihex-5-enyl 5-iodoisophthalate 、 2,2-Bi噻吩-5,5-二硼酸 在 palladium diacetate 、 potassium carbonate 、 三(邻甲基苯基)磷 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 生成 Bis(hex-5-enyl) 5-[5-[5-[3,5-bis(hex-5-enoxycarbonyl)phenyl]thiophen-2-yl]thiophen-2-yl]benzene-1,3-dicarboxylate
  参考文献：
  名称：

  Molecular Design and Preparation of Bis-isophthalate Electrochromic Systems having Controllable Color and Bistability

  摘要：

  New electrochromic systems based on bis-isophthalates were designed and prepared. They showed electrochromism behavior by two-electron reduction. The displayed colors showed greatly enhanced bistability and were dependent on the length of the conjugated bridge between the two isophthalate groups. We believe that the connection of two electrochromic systems with a conjugated bridge is a good basic strategy to obtain new bistable electrochromic systems.

  DOI：

  10.1021/ol802208x

文献信息

• ELECTROCHROMIC MATERIALS AND ELECTROCHROMIC DEVICES USING THE SAME
  申请人：SON Seung Uk

  公开号：US20100039025A1

  公开（公告）日：2010-02-18

  Disclosed herein are novel electrochromic materials. The electrochromic materials produce various colors and have bistability to achieve red-green-blue full colors. Therefore, the electrochromic materials can be used in a variety of electrochromic devices. Also disclosed herein are electrochromic devices fabricated using the electrochromic materials.
• US8274213B2
  申请人：——

  公开号：US8274213B2

  公开（公告）日：2012-09-25
• US9228124B2
  申请人：——

  公开号：US9228124B2

  公开（公告）日：2016-01-05