Benzene, 1,1'-[(methylsulfinyl)ethenylidene]bis-, (S)- | 142407-31-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzene, 1,1'-[(methylsulfinyl)ethenylidene]bis-, (S)-
• 英文别名: (S)-(-)-methyl-(2,2-diphenyl) vinyl sulfoxide
• CAS: 142407-31-6
• 化学式: C₁₅H₁₄OS
• 分子量: 242.342
• InChiKey: PSFYWDKTTTYRIS-KRWDZBQOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.45
• 重原子数：
  17.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  1,1'-[2-(甲硫基)-1,1-乙烯二基]二苯 在 (-)-α,α-dichlorocamphorbenzenesulfonyloxaziridine 作用下， 以 二氯甲烷 为溶剂， 反应 6.0h， 生成 Benzene, 1,1'-[(methylsulfinyl)ethenylidene]bis-, (S)- 、 Benzene, 1,1'-[(methylsulfinyl)ethenylidene]bis-, (S)-
  参考文献：
  名称：

  Microbiological and chemical methods in the asymmetric oxidation of sulfides: A comparative study for the preparation of (S)-vinyl sulfoxides

  摘要：

  The enantiogenicity of biological and chemical oxidation at the sulfur atom was studied on a series of prochiral vinyl sulfides for the preparation of sulfoxides of (S)-absolute configuration. Using either fungal cultures, Sharpless-modified reagent or chiral oxaziridine, the enantiomeric excesses varied according to the substrate's steric and/or electronic structure; the three methods were complementary.

  DOI：

  10.1016/s0957-4166(00)82296-x

文献信息

• Microbiological and chemical methods in the asymmetric oxidation of sulfides: A comparative study for the preparation of (S)-vinyl sulfoxides
  作者：Claude Rossi、Annie Fauve、Michel Madesclaire、Danielle Roche、Franklin A. Davis、R. Thimma Reddy

  DOI：10.1016/s0957-4166(00)82296-x

  日期：1992.5

  The enantiogenicity of biological and chemical oxidation at the sulfur atom was studied on a series of prochiral vinyl sulfides for the preparation of sulfoxides of (S)-absolute configuration. Using either fungal cultures, Sharpless-modified reagent or chiral oxaziridine, the enantiomeric excesses varied according to the substrate's steric and/or electronic structure; the three methods were complementary.