丙酸乙酯(2-甲基丙烯酸酯) | 102908-80-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 丙酸乙酯(2-甲基丙烯酸酯)
• 英文名称: (2-methacrylate) of propanoate ethyl
• 英文别名: O-methacryloyl-lactic acid ethyl ester；2-Methacryloyloxy-propionsaeure-aethylester；O-Methacryloyl-milchsaeure-aethylester；(1-Ethoxy-1-oxopropan-2-yl) 2-methylprop-2-enoate
• CAS: 102908-80-5
• 化学式: C₉H₁₄O₄
• 分子量: 186.208
• InChiKey: IQGQDACEKUMDRQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-(α-acetoxy-isobutyryloxy)-propionic acid ethyl ester 生成 丙酸乙酯(2-甲基丙烯酸酯)
  参考文献：
  名称：

  Filachione; Lengel; Fisher, Journal of the American Chemical Society, 1946, vol. 68, p. 332

  摘要：

  DOI：

文献信息

• A CONVENIENT HIGH YIELD SYNTHESIS OF FUNCTIONAL METHACRYLATES <i>VIA</i> DETHIOACETALIZATION. SYNTHESIS OF METHACRYLATE S,S-ACETAL DERIVATIVES AS INTERMEDIATES
  作者：Florence Caye、Michèle Sindt、Jean-Luc Mieloszynski、Daniel Paquer

  DOI：10.1080/10426509808045498

  日期：1998.12.1

  Abstract We describe a selective and efficient synthesis of a whole new class of functional methacrylates starting from S,S-acetals. Carbonyl compounds were regenerated from corresponding S,S-acetals using mercury (11) salts. According to this method, methacrylic sensitive group (possible polymerization), is not affected.

  摘要 我们描述了一种以 S,S-缩醛为原料选择性和高效合成一类全新的功能性甲基丙烯酸酯的方法。使用汞 (11) 盐从相应的 S,S-缩醛中再生羰基化合物。根据该方法，甲基丙烯酸敏感基团（可能聚合）不受影响。
• Resist composition for immersion exposure, method of forming resist pattern using the same, and fluorine-containing compound
  申请人：Tokyo Ohka Kogyo Co., Ltd.

  公开号：EP2088466A1

  公开（公告）日：2009-08-12

  A resist composition for immersion exposure, including a base component (A) that exhibits changed solubility in an alkali developing solution under action of acid, an acid generator component (B) that generates acid upon exposure, and a fluorine-containing compound (C) represented by a general formula (c-1) shown below that is decomposable in an alkali developing solution: wherein R1 represents an organic group which may contain a polymerizable group, with the proviso that said polymerizable group has a carbon-carbon multiple bond, and the carbon atoms forming the multiple bond are not directly bonded to the carbon atom within the -C(=O)- group in general formula (c-1); and R2 represents an organic group having a fluorine atom.

  一种用于浸泡曝光的抗蚀剂组合物，包括在酸的作用下在碱显影液中的溶解度发生变化的碱成分（A）、在曝光时产生酸的酸生成成分（B）、以及可在碱显影液中分解的由下图所示通式（c-1）表示的含氟化合物（C）： 其中 R1 代表可含有可聚合基团的有机基团，但条件是所述可聚合基团具有碳-碳多键，且形成多键的碳原子与通式（c-1）中 -C(=O)- 基团内的碳原子不直接成键；R2 代表具有氟原子的有机基团。
• RESIST COMPOSITION FOR IMMERSION EXPOSURE, METHOD OF FORMING RESIST PATTERN USING THE SAME, AND FLUORINE-CONTAINING COMPOUND
  申请人：Shiono Daiju

  公开号：US20090197204A1

  公开（公告）日：2009-08-06

  A resist composition for immersion exposure, including a base component (A) that exhibits changed solubility in an alkali developing solution under action of acid, an acid generator component (B) that generates acid upon exposure, and a fluorine-containing compound (C) represented by a general formula (c-1) shown below that is decomposable in an alkali developing solution: wherein R 1 represents an organic group which may contain a polymerizable group, with the proviso that said polymerizable group has a carbon-carbon multiple bond, and the carbon atoms forming the multiple bond are not directly bonded to the carbon atom within the —C(═O)— group in general formula (c-1); and R 2 represents an organic group having a fluorine atom.
• Viscous alpha-Cyanoacrylate Compositions
  申请人：BADEJO Ibraheem T.

  公开号：US20090326095A1

  公开（公告）日：2009-12-31

  A polymerizable adhesive composition comprises at least one α-cyanoacrylate monomer and at least one absorbable viscosity modifying agent. The absorbable viscosity modifying agent has repeated units of the following structure: R 1 is a methyl group or a hydrogen. R 2 is a straight, branched or cyclic alkyl group having from 1 to 6 carbon atoms. R 3 is a straight, branched or cyclic alkyl group having from 1 to 12 carbon atoms, and n is 2 or more.
• US7932305B2
  申请人：——

  公开号：US7932305B2

  公开（公告）日：2011-04-26