1-methyl-3-(4-vinylbenzyl)imidazolium iodide | 1200703-15-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-methyl-3-(4-vinylbenzyl)imidazolium iodide
• CAS: 1200703-15-6
• 化学式: C₁₃H₁₅N₂*I
• 分子量: 326.18
• InChiKey: PSCIOCSVMYQZDS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.99
• 重原子数：
  16.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  8.81
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  1-methyl-3-(4-vinylbenzyl)imidazolium iodide 、 silver(l) oxide 以 丙酮 为溶剂， 以22%的产率得到[(silver(I)(1-methyl-3-(4-vinylbenzyl)imidazol-2-ylidene)2)2(silver(I))2(iodide)4]
  参考文献：
  名称：

  Synthesis and structures of mono- and tetra-nuclear silver complexes of styrene-containing N-heterocyclic carbene

  摘要：

  Two tetra-nuclear Ag(I) complexes with styrene-functionalized N-heterocyclic carbene [AgL2](2)[Ag2X4] (L = 1-methyl-3-(4-vinylbenzyl)imidazol-2-ylidene, X = Cl, 2a; X = I, 2b) were prepared by the reactions between the corresponding imidazolium salts with Ag2O. The reaction mixture was further treated with AgBF4 to give a mononuclear ion-pair complex [AgL2][BF4] (3). The molecular structures of these new Ag(I) complexes have been determined by X-ray diffraction analyses. 2a and 2b consist of two [Ag(L)(2)](+) fragments with the central [Ag2X4](2-) anion held together by the close Ag(I)-Ag(I) interactions. Complex 3 is a mononuclear ion-pair complex with a linear bi-coordinate Ag fragment. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.07.016