trans-(bis{[4-(2-{4-[2-(1-{2-[(tert-butyldiphenylsilyl)oxy]ethyl}-1H-1,2,3-triazol-4-yl)ethynyl]phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum | 1429466-19-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-(bis{[4-(2-{4-[2-(1-{2-[(tert-butyldiphenylsilyl)oxy]ethyl}-1H-1,2,3-triazol-4-yl)ethynyl]phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum
• CAS: 1429466-19-2
• 化学式: C₁₀₀H₁₁₈N₆O₂P₂PtSi₂
• 分子量: 1749.27
• InChiKey: OEFUHEYGQHRWJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-(bis{[4-(2-{4-[2-(1-{2-[(tert-butyldiphenylsilyl)oxy]ethyl}-1H-1,2,3-triazol-4-yl)ethynyl]phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum 在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以84%的产率得到trans-[bis({4-[2-(4-{2-[1-(2-hydroxyethyl)-1H-1,2,3-triazol-4-yl]ethynyl}phenyl)ethynyl]-phenyl}ethyne) bis(tri-n-butylphosphine)] platinum
  参考文献：
  名称：

  Synthesis, optical power limiting, and DFT calculations of triplet–triplet absorption of three novel Pt(II)-diacetylide chromophores

  摘要：

  Three novel rod-like Pt(II)-diacetylides have been synthesized. When subjected to intense laser light, all three compounds showed strong optical power limiting at 532 and 600 nm. DFT calculated triplet-triplet electronic excitations were found to correlate with the nonlinear absorption. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.02.105
• 作为产物：
  描述：

  trans-dichloro-bis(tri-n-butylphosphine)platinum(II) 、 1-{2-[(tert-butyldiphenylsilyl)oxy]ethyl}-4-(2-{4-[2-(4-ethynylphenyl)ethynyl]phenyl}ethynyl)-1H-1,2,3-triazole 在 三乙胺 、 copper(l) iodide 作用下， 以 四氢呋喃 为溶剂， 反应 0.29h， 以54%的产率得到trans-(bis{[4-(2-{4-[2-(1-{2-[(tert-butyldiphenylsilyl)oxy]ethyl}-1H-1,2,3-triazol-4-yl)ethynyl]phenyl}ethynyl)phenyl]ethyne}bis(tri-n-butylphosphine))platinum
  参考文献：
  名称：

  Synthesis, optical power limiting, and DFT calculations of triplet–triplet absorption of three novel Pt(II)-diacetylide chromophores

  摘要：

  Three novel rod-like Pt(II)-diacetylides have been synthesized. When subjected to intense laser light, all three compounds showed strong optical power limiting at 532 and 600 nm. DFT calculated triplet-triplet electronic excitations were found to correlate with the nonlinear absorption. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.02.105