4-[difluoro(3,4,5-trifluorophenoxy)methyl]-4'''-n-pentyl-2',2'',3,5-tetrafluoro-1,1',4',1'',4'',1'''-quaterphenyl | 1052241-41-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[difluoro(3,4,5-trifluorophenoxy)methyl]-4'''-n-pentyl-2',2'',3,5-tetrafluoro-1,1',4',1'',4'',1'''-quaterphenyl
• 英文别名: 2-[Difluoro-(3,4,5-trifluorophenoxy)methyl]-1,3-difluoro-5-[2-fluoro-4-[2-fluoro-4-(4-pentylphenyl)phenyl]phenyl]benzene
• CAS: 1052241-41-4
• 化学式: C₃₆H₂₅F₉O
• 分子量: 644.58
• InChiKey: JGXAAQKBUSBMPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.1
• 重原子数：
  46
• 可旋转键数：
  10
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  2',3-difluoro-4"-pentyl-1,1',4',1"-terphenyl 、 3,5-二氟苯硼酸 在 正丁基锂 、 碘 、 仲丁基锂 作用下， 生成 4-[difluoro(3,4,5-trifluorophenoxy)methyl]-4'''-n-pentyl-2',2'',3,5-tetrafluoro-1,1',4',1'',4'',1'''-quaterphenyl
  参考文献：
  名称：

  Nematic Liquid Crystal Compounds with Five-Ring Framework

  摘要：

  A series of novel liquid crystal compounds with five-ring framework having a -CF(2)O- linkage group (1a-1e) has been synthesized and their physical properties were measured. These compounds are characterized to have higher nematic-isotropic liquid transition temperatures and broader mesophase temperature range. As for the anisotropic properties, this series is categorized as compounds having large Delta epsilon and Delta n. Although these compounds possess five rings in their structures, they exhibit high miscibility caused by the rotately non-symmetric structures including the lateral fluorine substituted phenylene rings. One of the novel compounds exhibits SmF phase and shows the second-order phase transition of SmA to SmC. The compounds are effective to improve the response property of the mixtures due to their high elastic constants. These five-ring compounds possess diversified properties and of high potential materials for improving the LCD performances.

  DOI：

  10.1080/15421400903065440

文献信息

• FIVE-RING LIQUID CRYSTAL COMPOUND HAVING CF20 BONDING GROUP, LIQUID CRYSTAL COMPOSITION, AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：Tanaka Hiroyuki

  公开号：US20100127211A1

  公开（公告）日：2010-05-27

  The invention provides a five-ring liquid crystal compound having a CF 2 O bonding group as a new compound having a general physical properties necessary for compounds, stability to heat, light and so forth, a wide temperature range of liquid crystal phases, a high clearing point, a good compatibility with other compounds, a large dielectric anisotropy and refractive index anisotropy, and an especially high clearing point and an especially large refractive index anisotropy, and provides a liquid crystal composition and a liquid crystal display device.

  本发明提供了一种具有CF2O键合基团的五环液晶化合物，作为一种具有化合物所需的一般物理性质、对热、光等的稳定性、广泛的液晶相温度范围、高清晰点、与其他化合物良好的相容性、大电介质各向异性和折射率各向异性，特别是高清晰点和特别大的折射率各向异性的新化合物，并提供了一种液晶组合物和液晶显示装置。
• Liquid crystal display device
  申请人：DIC CORPORATION

  公开号：US10011773B2

  公开（公告）日：2018-07-03

  The present invention relates to a liquid crystal display device that includes a particular color filter containing a material containing chiral liquid crystals and a particular dye and/or pigment. The present invention provides a liquid crystal display device that can prevent a decrease in the voltage holding ratio (VHR) of a liquid crystal layer and solve the problem of display defects, such as white spots, variations in alignment, and burn-in. Because liquid crystal display devices according to the present invention characteristically prevent a decrease in the voltage holding ratio (VHR) of a liquid crystal layer and reduces the occurrence of display defects, such as burn-in, the liquid crystal display devices are particularly useful as liquid crystal display devices in IPS mode and FFS mode for active-matrix driving and can be applied to household electrical appliances, automobiles, production facilities, measuring and analytical instruments, and communication devices.

  本发明涉及一种液晶显示装置，其中包括一种特定的彩色滤光片，该滤光片含有手性液晶和特定染料和/或颜料的材料。 本发明提供的液晶显示装置可防止液晶层的电压保持率（VHR）下降，并解决显示缺陷问题，如白斑、排列变化和烧损。 由于根据本发明的液晶显示装置具有防止液晶层的电压保持比（VHR）降低和减少显示缺陷（如烧毁）发生的特点，因此该液晶显示装置特别适用于有源矩阵驱动的 IPS 模式和 FFS 模式的液晶显示装置，并可应用于家用电器、汽车、生产设备、测量和分析仪器以及通信设备。
• PENTACYCLIC LIQUID CRYSTAL COMPOUND HAVING CF<SB>2</SB>O BONDING GROUP, LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY
  申请人：JNC Corporation

  公开号：EP2116522B1

  公开（公告）日：2013-09-18
• OPTICALLY ISOTROPIC LIQUID CRYSTAL MEDIUM AND OPTICAL DEVICE
  申请人：HASEBA YASUHIRO

  公开号：US20090059157A1

  公开（公告）日：2009-03-05

  A liquid crystal medium is described, which has stability to heat, light and so on, a wide temperature range of liquid crystal phase, a large optical anisotropy and a large dielectric anisotropy, and exhibits an optically isotropic liquid crystal phase. The liquid crystal medium includes a liquid crystal compound represented by formula (1) and a chiral reagent and exhibits an optically isotropic liquid crystal phase. For example, R 1 is C 1 -C 20 alkyl; the rings A 1 -A 6 are each 1,4-cyclohexylene, 1,3-dioxan-2,5-diyl, 1,4-phenylene, or 1,4-phenylene with arbitrary hydrogen atom being replaced by a halogen atom; Z 1 -Z 6 are each a single bond; L 1 -L 4 are each a hydrogen atom or a halogen atom; X 1 is a hydrogen atom or a halogen atom; each of l, m, n, o, p and q is 0 or 1, and the sum of them is 3.
• OPTICALLY ISOTROPIC LIQUID CRYSTAL COMPOSITION AND OPTICAL DEVICE
  申请人：JNC CORPORATION

  公开号：US20150240159A1

  公开（公告）日：2015-08-27

  A liquid crystal composition is described, containing a chiral agent and achiral component T containing at least one compound 1 having an unsubstituted or methyl group-substituted dioxane ring and having at least one —COO— or —CF 2 O— as a connecting group, and exhibiting an optically isotropic liquid crystal phase.