4-[二氟(3,4,5-三氟苯氧基)甲基]-2',3,5-三氟-4''-戊基-1,1':4',1''-三联苯 | 916156-32-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-[二氟(3,4,5-三氟苯氧基)甲基]-2',3,5-三氟-4''-戊基-1,1':4',1''-三联苯
• 英文名称: 4-[difluoro-(3,4,5-trifluorophenoxy)methyl]-2',3,5-trifluoro-4"-pentyl-[1,1';4',1"]terphenyl
• 英文别名: 4-(difluoro(3,4,5-trifluorophenoxy)methyl)-3,5,2'-trifluoro-4''-pentyl[1,1';4',1'']terphenyl；4-[difluoro(3,4,5-trifluorophenoxy)methyl]-2',3,5-trifluoro-4''-pentyl-1,1':4',1''-Terphenyl；2-[difluoro-(3,4,5-trifluorophenoxy)methyl]-1,3-difluoro-5-[2-fluoro-4-(4-pentylphenyl)phenyl]benzene
• CAS: 916156-32-6
• 化学式: C₃₀H₂₂F₈O
• 分子量: 550.491
• InChiKey: KOFASFPAZGQDKP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  39
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  3,5-二氟苯硼酸 在 正丁基锂 、 potassium carbonate 作用下， 以 四氢呋喃 、 水 为溶剂， 生成 4-[二氟(3,4,5-三氟苯氧基)甲基]-2',3,5-三氟-4''-戊基-1,1':4',1''-三联苯
  参考文献：
  名称：

  Novel Liquid Crystalline Four Ring Chain Difluoromethyleneoxy Compounds for Quicker Response LC Mixtures

  摘要：

  A series of chemically stable novel liquid crystalline four ring chain compounds (1a-1c) having a difluoromethyleneoxy (CF(2)O) linkage moiety have been designed and prepared, and their properties have been thoroughly investigated. The novel compounds intrinsically possess much higher positive Delta epsilon (>32) and Delta n (>0.190), relatively low viscosity, wider nematic phase temperature ranges and significantly higher clearing temperatures in comparison to the analogous three ring chain CF(2)O compound (2) that is currently applied in almost all the latest TN-TFT monitors, notebook PCs and IPS-TVs.

  DOI：

  10.1080/15421400903065200

文献信息

• COMPOUNDS HAVING A DIFLUOROCYCLOHEXANE RING, LIQUID CRYSTAL COMPOSITIONS AND LIQUID CRYSTAL DISPLAY DEVICES
  申请人：JNC CORPORATION

  公开号：US20170240809A1

  公开（公告）日：2017-08-24

  The invention provides a liquid crystal compound satisfying at least one of physical properties such as a high stability to heat or light, a high clearing point (or a high maximum temperature), a low minimum temperature of a liquid crystal phase, a small viscosity, a suitable optical anisotropy, a small dielectric anisotropy, a suitable elastic constant and a good compatibility with other liquid crystal compounds, a liquid crystal composition including this compound, and a liquid crystal display device containing this composition. The invention provdes a compound represented by formula (1): where R 1 and R 2 is alkyl having 1 to 20 carbons or the like; one of L 1 and L 2 is both hydrogens, and the other is both fluorines; Z 1 and Z 2 are independently a single bond, —COO—, —OCO—, —OCH 2 —, —CH 2 O—, —CF 2 O—, —OCF 2 —, —CH 2 CH 2 —, —CH═CH—, —C≡C— or the like.

  该发明提供了一种液晶化合物，满足以下至少一种物理性质：对热或光的高稳定性，高清晰点（或高最高温度），液晶相的低最低温度，低粘度，适当的光学各向异性，小介电各向异性，适当的弹性常数以及与其他液晶化合物的良好兼容性，包括这种化合物的液晶组合物，以及含有这种组合物的液晶显示装置。该发明提供了一种由以下式（1）表示的化合物：其中R1和R2是具有1至20个碳原子的烷基或类似物；L1和L2中的一个是两个氢，另一个是两个氟；Z1和Z2独立地是单键，—COO—，—OCO—，—OCH2—，—CH2O—，—CF2O—，—OCF2—，—CH2CH2—，—CH═CH—，—C≡C—或类似物。
• LIQUID CRYSTAL COMPOUND, LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY DEVICE
  申请人：GOTO Shuichi

  公开号：US20110180756A1

  公开（公告）日：2011-07-28

  The subject is to provide a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a suitable optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light, a high stability to heat and a large elastic constant, or that is suitably balanced regarding at least two of the characteristics. The subject is to provide an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth. The invention provides a liquid crystal composition that has a nematic phase and includes a specific four-ring compound having a high maximum temperature and a large dielectric anisotropy as a first component and a specific compound having a small dielectric anisotropy as a second component, and also provides a liquid crystal display device containing this composition. The invention further provides the compound of the first component.

  本主题是提供一种液晶组合物，满足至少以下特性之一：向列相的最高温度高，向列相的最低温度低，粘度小，适当的光学各向异性，大的介电各向异性，大的特定电阻，对紫外光稳定性高，对热稳定性高以及大的弹性常数，或者在至少两个特性中适当平衡。本主题是提供一种具有短响应时间、大电压保持比、大对比度、长寿命等特性的AM装置。该发明提供了一种具有向列相的液晶组合物，包括具有高最高温度和大介电各向异性的特定四环化合物作为第一组分，以及具有小介电各向异性的特定化合物作为第二组分，并且提供了含有该组合物的液晶显示装置。该发明还提供了第一组分的化合物。
• LIQUID-CRYSTALLINE MEDIUM
  申请人：MERCK PATENT GMBH

  公开号：US20150315472A1

  公开（公告）日：2015-11-05

  The invention relates to compounds of the formula I and to a liquid-crystalline medium which comprises one or more compounds of the formula I, in which R 1 , X 1 , X, Y 1 and Y 2 have the meanings indicated in Claim 1 , and to the use thereof for electro-optical purposes, in particular for shutter glasses, 3D applications, in TN, PS-TN, STN, TN-TFT, OCB, IPS, PS-IPS, FFS, PS-FFS and PS-VA-IPS displays.

  本发明涉及公式I的化合物以及包含一个或多个公式I的液晶介质，其中R1、X1、X、Y1和Y2具有权利要求1中所示的含义，并且本发明涉及将其用于电光目的，特别是用于快门眼镜、3D应用程序，在TN、PS-TN、STN、TN-TFT、OCB、IPS、PS-IPS、FFS、PS-FFS和PS-VA-IPS显示器中。
• LIQUID CRYSTAL COMPOSITION AND LIQUID CRYSTAL DISPLAY ELEMENT
  申请人：Hattori Norikatsu

  公开号：US20120169974A1

  公开（公告）日：2012-07-05

  The invention is to provide a liquid crystal composition that satisfies at least one of characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large positive dielectric anisotropy, a large specific resistance, a large elastic coefficient, a high stability to ultraviolet light and heat, or that is suitably balanced between at least two of the characteristics. As the liquid crystal display device containing the compositions is to provide an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth, thus it can be used for the liquid crystal projector, liquid crystal television and so forth.

  本发明旨在提供一种液晶组合物，其具有高向列相最高温度、低向列相最低温度、小粘度、大光学各向异性、大正电介质各向异性、大特定电阻、大弹性系数、高抗紫外线和热稳定性等特性之一，或在至少两种特性之间适当平衡。由于含有该组合物的液晶显示器件可提供具有短响应时间、大电压保持比、大对比度、长使用寿命等特点的AM器件，因此它可用于液晶投影仪、液晶电视等领域。
• COMPOUND HAVING BRANCHED ALKYL OR BRANCHED ALKENYL, OPTICALLY ISOTROPIC LIQUID CRYSTAL MEDIUM AND OPTICAL ELEMENT
  申请人：JNC Corporation

  公开号：EP2586764A1

  公开（公告）日：2013-05-01

  The first object of the invention is to provide a liquid crystal compound that is stable to heat, light and so on, and has a large optical anisotropy, a large dielectric anisotropy and a low melting point. The second object is to provide a liquid crystal medium that is stable to heat, light and so on, has a broad temperature range of a liquid crystal phase, a large optical anisotropy and a large dielectric anisotropy, and exhibits an optically isotropic liquid crystal phase. The third object is to provide a variety of optical elements containing the liquid crystal medium, which can be used in a broad temperature range and has a short response time, a high contrast and a low driving voltage. A liquid crystal compound with branched alkyl or branched alkenyl as represented by formula (1), a liquid crystal medium (a liquid crystal composition or a polymer/liquid crystal composite material) containing the liquid crystal compound, and an optical element containing the liquid crystal medium are described. In formula (1), R1 is branched alkyl of C3-20 or branched alkenyl of C3-20. The ring A1, A2, A3, A4 or A5 is 1,4-phenylene or 1,3-dioxane-2,5-diyl, for example. Z1, Z2, Z3 and Z4 are independently a single bond or C1-4 alkylene, for example. Y1 is fluorine, for example, m, n and p are independently 0 or 1, and 1≤m+n+p≤3.

  本发明的第一个目的是提供一种液晶化合物，它对热、光等都很稳定，具有较大的光学各向异性、较大的介电各向异性和较低的熔点。第二个目的是提供一种液晶介质，该介质对热、光等稳定，具有宽温度范围的液晶相、大的光学各向异性和大的介电各向异性，并呈现光学各向同性液晶相。第三个目的是提供含有该液晶介质的各种光学元件，它可在宽温度范围内使用，响应时间短，对比度高，驱动电压低。 本发明描述了由式（1）表示的具有支链烷基或支链烯基的液晶化合物、含有该液晶化合物的液晶介质（液晶组合物或聚合物/液晶复合材料）以及含有该液晶介质的光学元件。 在式 (1) 中，R1 是 C3-20 的支链烷基或 C3-20 的支链烯基。环 A1、A2、A3、A4 或 A5 是 1,4-亚苯基或 1,3-二氧六环-2,5-二基。Z1、Z2、Z3 和 Z4 独立地为单键或 C1-4 亚烷基等。Y1是氟，例如，m、n和p独立地为0或1，且1≤m+n+p≤3。