3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-nonadecafluoro-1-dodecene | 1200407-69-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-nonadecafluoro-1-dodecene
• 英文别名: 3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-Nonadecafluorododec-1-ene；3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-nonadecafluorododec-1-ene
• CAS: 1200407-69-7
• 化学式: C₁₂H₅F₁₉
• 分子量: 510.141
• InChiKey: PGMPXFZVLSVGCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  31
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  19

反应信息

• 作为反应物：
  描述：

  3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-nonadecafluoro-1-dodecene 、 亚磷酸二乙酯 在 二叔丁基过氧化物 作用下， 反应 1.0h， 以77%的产率得到12-[Diethoxy(oxido)phosphaniumyl]-1,1,1,2,2,3,3,4,4,6,6,7,7,8,8,9,9,10,10-nonadecafluorododecane
  参考文献：
  名称：

  POLYFLUOROALKYLPHOSPHONIC ACID ESTER AND PROCESS FOR PRODUCING THE SAME

  摘要：

  通过将通用公式表示的多氟烷基磷酸酯与通用公式表示的三烷基磷酸酯反应，生产一种多氟烷基磷酸酯，该多氟烷基磷酸酯的通用公式为：CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2（R是具有1至4个碳原子的烷基基团，n是1至6的整数，a是1至4的整数，b是1至3的整数，c是1至3的整数）。或者通过将通用公式表示的多氟-1-烯与通用公式表示的二烷基磷酸酯反应，生产该多氟烷基磷酸酯。

  公开号：

  US20120108849A1
• 作为产物：
  描述：

  1,1,2,2,3,3,4,4,5,5,6,6,7,7,9,9,10,10,10-nonadecafluoro-1-iododecane 在 二叔丁基过氧化物 、 四丁基氯化铵 、 sodium hydroxide 作用下， 以 水 为溶剂， 20.0~115.0 ℃ 、500.01 kPa 条件下， 反应 75.0h， 生成 3,3,4,4,5,5,6,6,7,7,9,9,10,10,11,11,12,12,12-nonadecafluoro-1-dodecene
  参考文献：
  名称：

  POLYFLUOROALKYLPHOSPHONIC ACID ESTER AND PROCESS FOR PRODUCING THE SAME

  摘要：

  通过将通用公式表示的多氟烷基磷酸酯与通用公式表示的三烷基磷酸酯反应，生产一种多氟烷基磷酸酯，该多氟烷基磷酸酯的通用公式为：CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2（R是具有1至4个碳原子的烷基基团，n是1至6的整数，a是1至4的整数，b是1至3的整数，c是1至3的整数）。或者通过将通用公式表示的多氟-1-烯与通用公式表示的二烷基磷酸酯反应，生产该多氟烷基磷酸酯。

  公开号：

  US20120108849A1

文献信息

• POLYFLUORO-1-ALKENE AND METHOD FOR PRODUCING THE SAME
  申请人：Sato Katsuyuki

  公开号：US20110077435A1

  公开（公告）日：2011-03-31

  A polyfluoro-1-alkene represented by the general formula: CF 3 (CF 2 ) n CH 2 (CF 2 ) m CH═CH 2 [I], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, is produced by reacting a polyfluoroalkyl iodide represented by the general formula: CF 3 (CF 2 ) n CH 2 (CF 2 ) m (CH 2 CH 2 )I [II], wherein n is an integer of 0 to 5, and m is an integer of 1 to 7, with an inorganic basic compound in the presence of a phase transfer catalyst. Alternatively, the polyfluoro-1-alkene is produced by reacting the polyfluoroalkyl iodide [II] with a nitrogen-containing organic basic compound, and is obtained product [I] as one fraction thereof. By the copolymerization of the polyfluoro-1-alkene with other fluorinated olefin monomers, a fluorine-containing copolymer having excellent light transmittance in the visible light range is formed.

  通式表示的多氟-1-烯烃：CF3(CF2)nCH2(CF2)mCH═CH2[I]，其中n为0至5的整数，m为1至7的整数，通过将通式表示的多氟烷基碘化物：CF3(CF2)nCH2(CF2)m(CH2CH2)I [II]，其中n为0至5的整数，m为1至7的整数，与无机碱性化合物在相转移催化剂的存在下反应而制得。另外，通过将多氟烷基碘化物[II]与含氮有机碱性化合物反应，得到产物[I]的一部分。通过将多氟-1-烯烃与其他氟代烯烃单体共聚合，形成具有在可见光范围内优异透光性的含氟共聚物。
• Polyfluoroalkadiene mixture and method for producing the same
  申请人：Unimatec Co., Ltd.

  公开号：US08163857B2

  公开（公告）日：2012-04-24

  A mixture of polyfluoroalkadienes represented by the general formulae: CF3(CF2)nCF═CH(CF2)m+1CH═CH2 [Ia] and CF3(CF2)n+1CH═CF(CF2)mCH═CH2 [Ib], wherein n is an integer of 0 to 5, and m is an integer of 0 to 6, is obtained as a mixture fraction of products [Ia] and [Ib] by reacting a polyfluoroalkyl iodide represented by the general formula: CF3(CF2)n+1CH2(CF2)m+1(CH2CH2)I [II], with an organic basic compound. The polyfluoroalkadiene mixture is compounds having a perfluoroalkyl group in which the number of successive CF2 groups is 5 or less, and is effectively used as a copolymerizable monomer in the production of resinous or elastomeric fluorine-containing copolymers, which are used as active ingredients of surface-treating agents, such as water- and oil-repellents and mold-release agents.

  通过将通式表示的多氟烷烯混合物反应多氟烷基碘化物与有机碱性化合物，得到由以下两种通式表示的多氟烷烯混合物：CF3(CF2)nCF═CH(CF2)m+1CH═CH2 [Ia] 和 CF3(CF2)n+1CH═CF(CF2)mCH═CH2 [Ib]，其中n为0至5的整数，m为0至6的整数。多氟烷烯混合物是一种具有连续CF2基团数不超过5的全氟烷基的化合物，可有效用作树脂或弹性氟含量共聚物的共聚单体，在表面处理剂的活性成分中得到应用，如水和油的防水剂和脱模剂。
• POLYFLUOROALKYLPHOSPHONIC ACID ESTERS AND PROCESSES FOR PRODUCTION OF SAME
  申请人：Unimatec Co., Ltd.

  公开号：EP2452945A1

  公开（公告）日：2012-05-16

  A polyfluoroalkylphosphonic acid ester represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2 (R is an alkyl group having 1 to 4 carbon atoms, n is an integer of 1 to 6, a is an integer of 1 to 4, b is an integer of 1 to 3, and c is an integer of 1 to 3) is produced by a process of reacting a polyfluoroalkyl iodide represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI with a trialkyl phosphite represented by the general formula: P(OR)3 or by a process of reacting a polyfluoro-1-alkene represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)bCH=CH2 with a dialkyl phosphite represented by the general formula: (RO)2P(O)H.

  由通式表示的多氟烷基膦酸酯：CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OR)2（R 是具有 1 至 4 个碳原子的烷基，n 是 1 至 6 的整数，a 是 1 至 4 的整数，b 是 1 至 3 的整数，c 是 1 至 3 的整数）是由通式为CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cI与通式如下的三烷基亚磷酸酯反应制得：P(OR)3或通式如下的多氟-1-烯与通式如下的三烷基亚磷酸酯反应的过程CnF2n+1(CH2CF2)a(CF2CF2)bCH=CH2 与通式为(RO)2P(O)H.
• GRAFT COPOLYMER AND MOLD-RELEASING AGENT COMPRISING SAME AS ACTIVE INGREDIENT
  申请人：Kaneumi Yoshiyama

  公开号：US20120090504A1

  公开（公告）日：2012-04-19

  Disclosed is a graft copolymer in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: C n F 2n+ (CH 2 CF 2 ) a (CF 2 CF 2 ) b CH═CH 2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3). The graft copolymer is an oligomer compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having, when used as an active ingredient of a mold-releasing agent, mold release performance equivalent to that of a compound having a perfluoroalkyl group containing 8 or more carbon atoms.
• US8377187B2
  申请人：——

  公开号：US8377187B2

  公开（公告）日：2013-02-19