4-methyl-N-[4-[(E)-2-[4-(4-methyl-N-[4-[(E)-2-[4-(4-methyl-N-(4-methylphenyl)anilino)phenyl]ethenyl]phenyl]anilino)phenyl]ethenyl]phenyl]-N-(4-methylphenyl)aniline | 1355320-77-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-methyl-N-[4-[(E)-2-[4-(4-methyl-N-[4-[(E)-2-[4-(4-methyl-N-(4-methylphenyl)anilino)phenyl]ethenyl]phenyl]anilino)phenyl]ethenyl]phenyl]-N-(4-methylphenyl)aniline
• CAS: 1355320-77-2
• 化学式: C₆₃H₅₅N₃
• 分子量: 854.15
• InChiKey: GHRDCJMZTUKUOM-YWNVXTCZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18
• 重原子数：
  66
• 可旋转键数：
  13
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-碘甲苯 在 1,10-菲罗啉 、 potassium tert-butylate 、 碘 、 copper(l) chloride 、 三氯氧磷 作用下， 以 四氢呋喃 、 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 14.0h， 生成 4-methyl-N-[4-[(E)-2-[4-(4-methyl-N-[4-[(E)-2-[4-(4-methyl-N-(4-methylphenyl)anilino)phenyl]ethenyl]phenyl]anilino)phenyl]ethenyl]phenyl]-N-(4-methylphenyl)aniline
  参考文献：
  名称：

  Synthesis and properties of novel hole-transporting materials with triphenylamine units

  摘要：

  Two novel organic hole-transporting materials have been synthesized by combination of triphenylamines (TPA) via pi-conjugated bonds using Wittig reaction. The structures were characterized by NMR, FT-IR and HRMS. The optical, electrochemical and thermal properties of the materials were studied in detail. The results show that these two compounds have blue emission, proper HOMO levels and high thermal stability. Furthermore, a quantum chemical calculation on electron distribution of the two compounds was performed, which suggests the current synthesized materials would be promising candidates for hole-transporting materials. (C) 2011 Shi Rong Wang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

  DOI：

  10.1016/j.cclet.2011.11.018

文献信息

• Electrophotographic photoreceptor and image forming apparatus
  申请人：Mitsubishi Chemical Corporation

  公开号：US10725391B2

  公开（公告）日：2020-07-28

  The present invention relates to an electrophotographic photoreceptor comprising: a conductive support; and a photosensitive layer disposed on the conductive support, wherein the photosensitive layer includes a polyester resin containing a dihydric phenol residue and a dicarboxylic acid residue, and the dihydric phenol residue includes at least one dihydric phenol residue selected from the group of the specific dihydric phenol residues, and the other specific dihydric phenol residue.

  本发明涉及一种电子照相感光器，包括：导电支架；以及设置在导电支架上的感光层，其中感光层包括含有二水酚残基和二羧酸残基的聚酯树脂，二水酚残基包括从特定二水酚残基和其他特定二水酚残基组中选出的至少一种二水酚残基。
• Electrophotographic photoreceptor, and electrophotographic cartridge and image forming apparatus including same
  申请人：Mitsubishi Chemical Corporation

  公开号：US10884348B2

  公开（公告）日：2021-01-05

  The present invention aims to provide an electrophotographic photoreceptor which is excellent in abrasion resistance against practical load and excellent in initial electrical properties, preferably further excellent in adhesion between layers by containing a polyester resin excellent in abrasion resistance, which is an electrophotographic photoreceptor containing a photosensitive layer and a conductive support, the electrophotographic photoreceptor containing a polyester resin having a specific structure α with a number average molecular weight of 15,000 or less and containing a divalent phenol residue and a divalent carboxylic acid residue.

  本发明的目的是提供一种电致发光感光体，该感光体具有优异的耐磨性和初始电性能，尤其是通过含有耐磨性优异的聚酯树脂而进一步提高了层间的附着力，该感光体是一种电致发光感光体，包含感光层和导电支架，该电致发光感光体含有一种聚酯树脂，该聚酯树脂具有特定结构α，其平均分子量在 15000 或以下，并含有二价苯酚残基和二价羧酸残基。
• Electrophotographic photoreceptor, electrophotographic photoreceptor cartridge and image forming apparatus
  申请人：Mitsubishi Chemical Corporation

  公开号：US11181838B2

  公开（公告）日：2021-11-23

  The present invention aims to provide an electrophotographic photoreceptor excellent in abrasion resistance and electrical properties, which uses polymers excellent in surface-active functions such as fluororesin dispersibility and electrical properties, and relates to an electrophotographic photoreceptor which contains a polymer containing a repeating unit represented by the following Formula (A1), provided that the definitions of X1, X2, R11 to R16 in Formula (A1), and R21 in Formula (A2) are shown in the specification

  本发明旨在提供一种耐磨性和电性能优异的电致发光感光体，该感光体使用的聚合物具有优异的表面活性功能，如荧光素分散性和电性能，本发明涉及一种电致发光感光体，该感光体含有一种聚合物，该聚合物含有由下式（A1）表示的重复单元，但下式（A1）中的X1、X2、R11至R16以及式（A2）中的R21的定义如说明书所示
• ELECTROPHOTOGRAPHIC PHOTO-RECEPTOR, ELECTROPHOTOGRAPHIC PHOTO-RECEPTOR CARTRIDGE, IMAGE-FORMING DEVICE, AND TRIARYLAMINE COMPOUND
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2881795B1

  公开（公告）日：2016-07-13
• ELECTROPHOTOGRAPHIC PHOTORECEPTOR, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE, IMAGE-FORMING APPARATUS, AND TRIARYLAMINE COMPOUND
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20150205217A1

  公开（公告）日：2015-07-23

  The present invention relates to an electrophotographic photoreceptor comprising an electroconductive support and at least a photosensitive layer formed on the support, wherein the photosensitive layer contains a specific charge transport substance.