o-(N.2-Hydroxy-α-Methylenebenzylideneimino)benzoic acid | 64192-74-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o-(N.2-Hydroxy-α-Methylenebenzylideneimino)benzoic acid
• 英文别名: H2Anth-ohap；N-(2-hydroxy-α-methylbenzylidene)anthranilic acid；2-{[1-(6-Oxocyclohexa-2,4-dien-1-ylidene)ethyl]amino}benzoic acid；2-[1-(2-hydroxyphenyl)ethylideneamino]benzoic acid
• CAS: 64192-74-1
• 化学式: C₁₅H₁₃NO₃
• 分子量: 255.273
• InChiKey: JDJRGXVPFKPXLP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  69.9
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [tris(triphenylphosphine) ruthenium(III) trichloride] 、 o-(N.2-Hydroxy-α-Methylenebenzylideneimino)benzoic acid 以 苯 为溶剂， 以60%的产率得到[ruthenium(III)chloride(PPh3)2(N-(2-oxo-α-methylbenzylidene)anthranilate)]
  参考文献：
  名称：

  Synthesis, Spectral, Catalytic, and Bioactivity Studies of Ruthenium(III) Complexes Containing ONO Donor Schiff Base Ligands

  摘要：

  New hexa-coordinated ruthenium(III) complexes of the type [RuX(EPh3)2L] (X [image omitted] Cl or Br; E [image omitted] P or As; L [image omitted] deprotonated dibasic tridentate Schiff base ligand) have been synthesized by the reactions of [RuCl3(PPh3)3], [RuCl3(AsPh3)3] or [RuBr3(AsPh3)3] with the appropriate Schiff bases. The Schiff bases were synthesized by the condensation of anthranilic acid with acetyl acetone/salicylaldehyde/o-vanillin/o-hydroxy acetophenone. The complexes were characterized by elemental analyses, spectral (FT-IR, electronic and EPR) electrochemical, and magnetic moment data. Catalytic activity of the complexes in the oxidation of alcohols and the antibacterial activity of the ligands and the complexes have also been studied.

  DOI：

  10.1080/15533174.2010.522880