| 121192-28-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 金属杂环化合物
• CAS: 121192-28-7
• 化学式: C₄H₁₂Ge₂S₂
• 分子量: 269.451
• InChiKey: RUTDNGCSSYVOLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.87
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  二甲基锗烷硫酮 以 solid matrix 为溶剂， 生成
  参考文献：
  名称：

  Generation, low-temperature stabilization, structure, and reactivity of intermediates with low-coordinated carbon, silicon, and germanium atoms

  摘要：

  The mechanisms of thermal and photochemical transformations of organic and organometallic compounds which pass through formation of different reactive intermediates were investigated by low-temperature matrix IR spectroscopy. Low-temperature matrix stabilization of the intermediates, the primary products of these reactions, was conducted at 10-15 K. The spectral and structural parameters of the free radicals (CCl3, CCl2Br, CClBr2, CH2CH=CH2, CF2CF=CF2, CH2-C=CH, CH2C=N, CH2Ph, CF2C6F5), halocarbenes and their silicon and germanium analogs, and unstable molecules with double-bond silicon and germanium atoms were obtained as a result.

  DOI：

  10.1007/bf00961022

文献信息

• Direct study of unstable dimethylgermathione, Me2GeS, by vacuum pyrolysis-MS and low temperature matrix IR spectroscopy
  作者：V.N. Khabashesku、S.E. Boganov、P.S. Zuev、O.M. Nefedov、J. Tamás、A. Gömöry、I. Besenyei

  DOI：10.1016/0022-328x(91)83060-h

  日期：1991.1

  Dimethylgermathione, Me2GeS (D1), has been studied by vacuum pyrolysis-MS and matrix isolation IR spectroscopy. The germathione D1 was generated in the gas phase by pyrolytic decomposition (730–900°C, 10−2 −10−3 Torr) of the trimer (Me2GeS)3 (D3) in a quartz pyrolyzer, coupled to the ionization chamber of mass spectrometer or to an optical helium cryostat, where pyrolysis products have been frozen

  Dimethylgermathione中，Me 2个GeS（d 1），已经研究了通过真空热解-MS和基质隔离IR光谱。杀菌剂D 1是在石英热解器中通过三聚体（Me 2 GeS）3（D 3）的热解分解（730-900°C，10 -2 -10 -3托）在气相中产生的。质谱仪的电离室或光学氦低温恒温器，其中热解产物已在12 K的氩气基质中冷冻。
• Matrix isolation and IR spectroscopy of germanethione Me2Ge:S
  作者：Jacques Barrau、V. Balaji、Josef Michl

  DOI：10.1021/om00110a033

  日期：1989.8
• Generation of dimethylgermathione and dimethylsilathione and their detection in the gas phase by photo-electron spectroscopy
  作者：C. Guimon、G. Pfister-Guillouzu、H. Lavayssiere、G. Dousse、J. Barrau、J. Satge

  DOI：10.1016/s0022-328x(00)99442-7

  日期：1983.6