9-硬脂基-9-磷杂双环[4.2.1]壬烷 | 99886-26-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 金属杂环化合物
• 中文名称: 9-硬脂基-9-磷杂双环[4.2.1]壬烷
• 英文名称: 9-Stearyl-9-phosphabicyclo(4.2.1)nonane
• 英文别名: 9-octadecyl-9-phosphabicyclo[4.2.1]nonane
• CAS: 99886-26-7
• 化学式: C₂₆H₅₁P
• 分子量: 394.7
• InChiKey: RHBPCOITPOBTBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.6
• 重原子数：
  27
• 可旋转键数：
  17
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Hydroformylation process
  申请人：——

  公开号：US20040122262A1

  公开（公告）日：2004-06-24

  A hydroformylation process comprising reacting a compound having at least one olefinic carbon-to-carbon bond with hydrogen and carbon monoxide in the presence of a cobalt catalyst, the hydroformylation process being carried out in one or more reactors, at least one of which comprises a gas cap region and a liquid-containing region while in use, characterized in that a sulphur-containing additive is present on the inside walls of the gas cap region of the at least one-reactor which comprises a gas cap region and a liquid-containing region. The sulphur-containing additive suppresses the formation of methane during the hydroformylation process.

  一种水合甲酰化过程，包括在钴催化剂存在下将至少含有一个烯烃碳-碳键的化合物与氢气和一氧化碳发生反应，水合甲酰化过程在一个或多个反应器中进行，其中至少一个包括在使用时具有气帽区和含液区，其特征在于至少一个反应器的气帽区内壁上存在含硫添加剂，该含硫添加剂抑制了水合甲酰化过程中甲烷的生成。
• HYDROFORMYLATION PROCESS
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP1444187B1

  公开（公告）日：2006-03-29
• HYDROFORMULATION PROCESS
  申请人：Mul Wilhelmus Peter

  公开号：US20100179231A1

  公开（公告）日：2010-07-15

  A hydroformylation process for the production of alcohols comprising reacting, in a reactor system comprising one or more feed streams, a reaction environment and an output stream, a feedstock composition comprising a compound having at least one olefinic carbon-to-carbon bond with hydrogen and carbon monoxide in the presence of an organophosphine modified cobalt hydroformylation catalyst, wherein the hydroformylation process is carried out in the reaction environment which comprises at least two reaction zones, comprising a first reaction zone, a second reaction zone and, optionally, one or more later reaction zones, wherein the molar ratio of hydrogen to carbon monoxide entering the first reaction zone is in the range of from 0.5 to 1.65, and wherein water is added into the reactor system.
• Catalytic Hydroformylation of Vinyl Terminated Polyolefins
  申请人：ExxonMobil Chemical Patents Inc.

  公开号：US20140088261A1

  公开（公告）日：2014-03-27

  This invention relates to a polyolefin composition comprising one or more of the following formulae: wherein the PO is the residual portion of a vinyl terminated macromonomer (VTM) having had a terminal unsaturated carbon of an allylic chain and a vinyl carbon adjacent to the terminal unsaturated carbon; and wherein the VTM is preferably a vinyl terminated polymer having greater than 30% allyl chain ends with an Mn of greater than 10,000.
• US4472534A
  申请人：——

  公开号：US4472534A

  公开（公告）日：1984-09-18