9-(4-(9,10-diphenylanthracen-7-yl)phenyl)-9H-carbazole | 1202059-35-5

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 9-(4-(9,10-diphenylanthracen-7-yl)phenyl)-9H-carbazole
• 英文别名: 2CzPPA；9-[4-(9,10-diphenyl-2-anthryl)phenyl]-9H-carbazole；9-[4-(9,10-diphenylanthracen-2-yl)phenyl]carbazole
• CAS: 1202059-35-5
• 化学式: C₄₄H₂₉N
• 分子量: 571.721
• InChiKey: DWJWPFZGNZHHNQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.4
• 重原子数：
  45
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  9-[4-(4,4,5,5-四甲基-1,3,2-二氧硼杂环戊烷-2-基)苯基]-9H-咔唑 、 2-溴-9,10-二苯基蒽 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 2.0h， 以73%的产率得到9-(4-(9,10-diphenylanthracen-7-yl)phenyl)-9H-carbazole
  参考文献：
  名称：

  N-phenyl-N-(4-9, 10-diphenylanthracen-7-yl) phenyl)benzenamine for Undoped Blue Organic Light-Emitting Diodes

  摘要：

  In this work, we have designed and synthesized blue emitting materials based on 9,10-diphenylanthracene with aryl amino group such as carbazole and triphenylamine by Suzuki cross-coupling reactions. To investigate the electroluminescent properties of them, devices were fabricated with a following sequence: Indium-tin-oxide (180 nm)/4,4'-bis[N-(1-naphthyl)-N-phenyl amino]biphenyl (50 nm)/Blue materials (30 nm)/bathophenanthroline (30 nm)/lithium quinolate (2 nm)/Al (100 nm). In particular, a device using N-phenyl-N-(4-(9,10-diphenylanthracen-7yl) phenyl) benzenamine showed an efficient blue emission with a luminous, power, and external quantum efficiency of 3.28 cd/A, 2.19 lm/W, and 1.91% at 20 mA/cm(2), respectively.

  DOI：

  10.1166/jnn.2016.12487

文献信息

• Composition, method for manufacturing thin film, and method for manufacturing light-emitting element
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US08231942B2

  公开（公告）日：2012-07-31

  It is an object to provide a composition in which an anthracene derivative is dissolved and a technique in which a thin film that has a favorable film quality is formed by a wet process using the composition. In addition, it is another object to manufacture a highly reliable light-emitting element using the composition at low cost with high productivity. A composition having a solvent and an anthracene derivative having one anthracene structure and one carbazolyl group which is bonded to the anthracene structure directly or through a phenyl group is formed. A thin film with a favorable film quality can be formed by a wet process using the composition. Accordingly, a highly reliable light-emitting element can be manufactured using such a thin film.

  提供一种组合物，其中溶解了蒽衍生物，并通过使用该组合物的湿法工艺形成具有良好薄膜质量的薄膜的技术是一种目标。此外，另一个目标是以低成本高生产率使用该组合物制造高可靠性的发光元件。该组合物包含溶剂和具有一个蒽结构和一个与蒽结构直接或通过苯基键合的氨基甲酰基团的蒽衍生物。使用该组合物可以通过湿法工艺形成具有良好薄膜质量的薄膜。因此，可以使用这种薄膜制造高可靠性的发光元件。
• Anthracene Derivative, Light-Emitting Element, Light-Emitting Device, and Electronic Appliance
  申请人：Kawakami Sachiko

  公开号：US20090267498A1

  公开（公告）日：2009-10-29

  Novel anthracene derivatives are provided. Further, a light-emitting element, a light-emitting device, and an electronic appliance each using the novel anthracene derivative are provided. Anthracene derivatives represented by general formulae (G11) and (G21) are provided. The anthracene derivatives represented by the general formulae (G11) and (G21) each emit blue light with high color purity and have a carrier-transporting property. Therefore, each of the anthracene derivatives represented by the general formulae (G11) and (G21) is suitable for use in a light-emitting element, a light-emitting device, and an electronic appliance.

  本发明提供了新型蒽衍生物。此外，还提供了使用新型蒽衍生物的发光元件、发光装置和电子设备。提供了由通式（G11）和（G21）表示的蒽衍生物。通式（G11）和（G21）所表示的蒽衍生物均具有高色纯度的蓝光发射和载流子传输特性。因此，通式（G11）和（G21）所表示的蒽衍生物均适用于发光元件、发光装置和电子设备中的使用。
• [EN] ANTHRACENE DERIVATIVE, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC APPLIANCE<br/>[FR] DÉRIVÉ D'ANTHRACÈNE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT ET APPAREIL ÉLECTRONIQUE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2009131199A1

  公开（公告）日：2009-10-29

  Novel anthracene derivatives are provided. Further, a light-emitting element, a light-emitting device, and an electronic appliance each using the novel anthracene derivative are provided. Anthracene derivatives represented by general formulae (G11) and (G21) are provided. The anthracene derivatives represented by the general formulae (G11) and (G21) each emit blue light with high color purity and have a carrier-transporting property. Therefore, each of the anthracene derivatives represented by the general formulae (G11) and (G21) is suitable for use in a light-emitting element, a light-emitting device, and an electronic appliance.

  提供了新型蒽衍生物。此外，提供了使用新型蒽衍生物的发光元件、发光装置和电子设备。提供了由通用式（G11）和（G21）表示的蒽衍生物。通用式（G11）和（G21）表示的蒽衍生物均具有高色纯度的蓝光发射和载流子传输性能。因此，通用式（G11）和（G21）表示的每个蒽衍生物都适用于用于发光元件、发光装置和电子设备。
• Composition, Method for Manufacturing Thin Film, and Method for Manufacturing Light-Emitting Element
  申请人：Shitagaki Satoko

  公开号：US20090317539A1

  公开（公告）日：2009-12-24

  It is an object to provide a composition in which an anthracene derivative is dissolved and a technique in which a thin film that has a favorable film quality is formed by a wet process using the composition. In addition, it is another object to manufacture a highly reliable light-emitting element using the composition at low cost with high productivity. A composition having a solvent and an anthracene derivative having one anthracene structure and one carbazolyl group which is bonded to the anthracene structure directly or through a phenyl group is formed. A thin film with a favorable film quality can be formed by a wet process using the composition. Accordingly, a highly reliable light-emitting element can be manufactured using such a thin film.

  本发明的目的是提供一种含有蒽衍生物溶解的组合物和一种利用该组合物通过湿法工艺形成具有良好薄膜质量的薄膜的技术。此外，另一个目的是使用该组合物以低成本和高生产率制造高可靠性的发光元件。所述组合物包含溶剂和具有一个蒽结构和一个咔唑基固定于蒽结构上，直接或通过苯基结构连接的蒽衍生物。使用该组合物可以通过湿法工艺形成具有良好薄膜质量的薄膜。因此，可以使用这样的薄膜制造高可靠性的发光元件。
• Anthracene derivative, light-emitting element, light-emitting device, and electronic appliance
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US09257654B2

  公开（公告）日：2016-02-09

  Novel anthracene derivatives are provided. Further, a light-emitting element, a light-emitting device, and an electronic appliance each using the novel anthracene derivative are provided. Anthracene derivatives represented by general formulae (G11) and (G21) are provided. The anthracene derivatives represented by the general formulae (G11) and (G21) each emit blue light with high color purity and have a carrier-transporting property. Therefore, each of the anthracene derivatives represented by the general formulae (G11) and (G21) is suitable for use in a light-emitting element, a light-emitting device, and an electronic appliance.

  本发明提供了新的蒽衍生物。此外，本发明还提供了使用新的蒽衍生物的发光元件、发光装置和电子设备。提供了由通式（G11）和（G21）表示的蒽衍生物。由通式（G11）和（G21）表示的蒽衍生物均具有高色纯度的蓝光发射和载流子传输性能。因此，由通式（G11）和（G21）表示的蒽衍生物均适用于用于发光元件、发光装置和电子设备。