除草剂BUMINAFOS | 51249-05-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 中文名称: 除草剂BUMINAFOS
• 英文名称: 1-n-Butylaminocyclohexyl-phosphonic acid-di-n-butylester
• 英文别名: 1-N-(butylamino)-cyclohexyl phosphonic acid dibutyl ester；dibutyl [1-(butylamino)cyclohexyl]phosphonate；di-n-butyl-1-n-butylamino-cyclohexyl-phosphonate；buminafos；N-butyl-1-dibutoxyphosphorylcyclohexan-1-amine
• CAS: 51249-05-9
• 化学式: C₁₈H₃₈NO₃P
• 分子量: 347.478
• InChiKey: NMBXMBCZBXUXAM-UHFFFAOYSA-N

物化性质

• 沸点：
  434.8±24.0 °C(Predicted)
• 密度：
  0.98±0.1 g/cm3(Predicted)
• 溶解度：
  4.89e-04 M
• 蒸汽压力：
  7.50e-04 mmHg

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  23
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  47.6
• 氢给体数：
  1
• 氢受体数：
  4

安全信息

• RTECS号：
  SZ6900000
• 海关编码：
  2931900090

制备方法与用途

类别：有毒物品

毒性分级：中毒

急性毒性：

• 口服-大鼠LD50: 3000 毫克/公斤
• 口服-小鼠LD50: 3475 毫克/公斤

可燃性危险特性：可燃；燃烧时会产生有毒的氮氧化物和磷氧化物烟雾

储运特性：库房需保持通风、低温且干燥

灭火剂：干粉、泡沫、砂土，二氧化碳，雾状水

上下游信息

• 下游产品

  中文名称	英文名称	CAS号	化学式	分子量
  ——	1-Aminocyclohexyl-phosphonic acid di-n-butylester	56372-37-3	C14H30NO3P	291.371

反应信息

• 作为反应物：
  描述：

  除草剂BUMINAFOS 生成 正丁醛
  参考文献：
  名称：

  LINSEL, GUNTER;LASS. MANN, GUNTER;DAMERAU, WERNER, Z. CHEM., 27,(1987) N 9, 340-341

  摘要：

  DOI：
• 作为产物：
  描述：

  N-cyclohexylidenebutylamine 、 亚磷酸二丁酯 生成 除草剂BUMINAFOS
  参考文献：
  名称：

  SYNTHESIS OF SOME NEW CYCLIC AMINOPHOSPHONATES AND THEIR PHYSIOLOGICAL ACTIVITIES

  摘要：

  The synthesis of 19 newly synthesized cyclic aminophosphonic acid derivatives was described and their biological activity studied. It was found, as in the case of the previously described series of acyclic analogues, that the phytotoxicity of the compounds, tested on aquatic plant Spirodela oligorrhiza depended mainly on their hydrophobic parameters. The most pronounced phytotoxicity, the measure of which was concentration of aminophosphonates causing 50% inhibition of plant growth (EC50), exhibited compounds with not too long hydrocarbon substituent on the nitrogen atom (8-10 carbon atoms) and branched propyl groups on the phosphorus atom. The test had preliminary character and permitted to eliminate the less promising compounds for further studies.

  DOI：

  10.1080/10426500108040237

文献信息

• Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto
  申请人：Dow AgroSciences LLC

  公开号：US20180279612A1

  公开（公告）日：2018-10-04

  This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

  这份披露涉及具有对节肢动物门、软体动物门和线虫门害虫具有杀虫效用的分子领域，用于生产此类分子的过程，用于此类过程的中间体，含有此类分子的杀虫组合物，以及使用此类杀虫组合物对抗此类害虫的过程。这些杀虫组合物可以用作螨虫剂、杀虫剂、螨虫剂、软体动物杀虫剂和线虫杀虫剂。本文件披露了具有以下式（“式一”）的分子。
• [EN] MOLECULES HAVING PESTICIDAL UTILITY, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES, RELATED THERETO<br/>[FR] MOLÉCULES PRÉSENTANT UNE UTILITÉ EN TANT QUE PESTICIDE, ET LEURS INTERMÉDIAIRES, COMPOSITIONS ET PROCÉDÉS
  申请人：DOW AGROSCIENCES LLC

  公开号：WO2017040194A1

  公开（公告）日：2017-03-09

  This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions aga inst such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula ("Formula One").

  这份披露涉及具有对节肢动物门、软体动物门和线虫门害虫有用的分子领域，用于生产这种分子的过程，用于这种过程的中间体，含有这种分子的杀虫剂组合物，以及使用这种杀虫剂组合物对抗这些害虫的过程。这些杀虫剂组合物可以用作螨虫剂、杀虫剂、螨虫剂、软体动物杀虫剂和线虫杀虫剂。本文件披露了具有以下化学式（“化学式一”）的分子。
• MOLECULES HAVING PESTICIDAL UTILITY, AND INTERMEDIATES, COMPOSITIONS, AND PROCESSES, RELATED THERETO
  申请人：Dow AgroSciences LLC

  公开号：US20170210723A1

  公开（公告）日：2017-07-27

  This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, compositions containing such molecules, and processes of using such molecules and compositions against such pests. These molecules and compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).

  这份披露涉及具有对节肢动物门、软体动物门和线虫门害虫具有杀虫效用的分子领域，用于生产这种分子的过程，用于这种过程的中间体，含有这种分子的组合物，以及使用这种分子和组合物对抗这些害虫的过程。这些分子和组合物可以用作杀螨剂、杀虫剂、杀螨剂、杀软体动物剂和杀线虫剂。本文件披露了具有以下式（“式一”）的分子。
• [EN] PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO<br/>[FR] COMPOSITIONS PESTICIDES ET PROCÉDÉS RELATIFS À CES COMPOSITIONS
  申请人：DOW AGROSCIENCES LLC

  公开号：WO2013009791A1

  公开（公告）日：2013-01-17

  This document discloses molecules having the following formula ("Formula One") The molecules disclosed in this document are related to the field of processes to produce molecules that are useful as pesticides (e.g., acaricides, insecticides, molluscicides, and nematicides), such molecules, and processes of using such molecules to control pests.

  这份文件公开了具有以下公式（“公式一”）的分子。本文档中披露的分子与生产作为农药（例如，杀螨剂、杀虫剂、杀软体动物剂和杀线虫剂）有用的分子的过程领域有关，以及这样的分子和使用这样的分子控制害虫的过程。
• Pesticidal Compositions and Processes Related Thereto
  申请人：Yap Maurice C.H.

  公开号：US20120110702A1

  公开（公告）日：2012-05-03

  This document discloses molecules having the following formula (“Formula One”): and processes related thereto.

  这份文件公开了具有以下公式（“公式一”）的分子以及与之相关的过程。