2,7-di-tert-butyl-7'-phenyl-8'H-spiro[fluorene-9,5'-indeno[2,1-c]fluoren]-8'-one | 1265228-03-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2,7-di-tert-butyl-7'-phenyl-8'H-spiro[fluorene-9,5'-indeno[2,1-c]fluoren]-8'-one
• CAS: 1265228-03-2
• 化学式: C₄₆H₃₈O
• 分子量: 606.807
• InChiKey: QVRYRWSTBTYXHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  47.0
• 可旋转键数：
  1.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  2,7-di-tert-butyl-7'-phenyl-8'H-spiro[fluorene-9,5'-indeno[2,1-c]fluoren]-8'-one 、 2-溴-4,4-二-叔丁基-1,1-联苯 在 正丁基锂 、 氯化铵 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 以93%的产率得到2,7-di-tert-butyl-8'-(4,4'-di-tert-butyl-[1,1'-biphenyl]-2-yl)-7'-phenyl-8'H-spiro[fluorene-9,5'-indeno[2,1-c]fluoren]-8'-ol
  参考文献：
  名称：

  Novel dispirobifluorenes and indeno-spirobifluorenes: syntheses and properties

  摘要：

  Novel indeno-spirobifluorene and dispirobifluorene derivatives were synthesized and characterized. Their two positional isomers were unambiguously determined by X-ray crystallography. Preliminary investigations indicated that these indeno-spirobifluorene and dispirobifluorenes showed blue fluorescence with good quantum yields (Phi>60%) and excellent thermal stabilities. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.11.092
• 作为产物：
  描述：

  2,7-di-tert-butyl-9-(1,4-diphenylfluoren-9-on-3-yl)fluoren-9-ol 在 溶剂黄146 、 盐酸 作用下， 以 水 为溶剂， 反应 2.0h， 以96%的产率得到2,7-di-tert-butyl-7'-phenyl-8'H-spiro[fluorene-9,5'-indeno[2,1-c]fluoren]-8'-one
  参考文献：
  名称：

  Novel dispirobifluorenes and indeno-spirobifluorenes: syntheses and properties

  摘要：

  Novel indeno-spirobifluorene and dispirobifluorene derivatives were synthesized and characterized. Their two positional isomers were unambiguously determined by X-ray crystallography. Preliminary investigations indicated that these indeno-spirobifluorene and dispirobifluorenes showed blue fluorescence with good quantum yields (Phi>60%) and excellent thermal stabilities. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2010.11.092